Clusters: A bridge across the disciplines of environment, materials science, and biology

  1. A. W. Castleman, Jr.*, and
  2. Puru Jena,
  1. *Departments of Chemistry and Physics, Pennsylvania State University, University Park, PA 16802; and
  2. Department of Physics, Virginia Commonwealth University, Richmond, VA 23284
  1. Edited by Jack Halpern, University of Chicago, Chicago, IL, and approved April 28, 2006 (received for review March 3, 2006)

  1. Fig. 1.

    Structure of the Si12W cluster. The W atom is sandwiched between two planar Si6 clusters.


  2. Fig. 2.

    Ionization potentials for the Ti8-xZrxC12 (x = 0–4, 8) clusters (61). [Reproduced with permission from ref. 61 (Copyright 1998, American Chemical Society).]


  3. Fig. 3.

    Mass spectra of Al cluster anions (A) reacted with I2 vapor (B) and etched with O2 (C). Peaks shaded green fall into the Al13Ix family, whereas peaks shaded blue fall into the Al14Ix family (64). In AC, the y-axis is peak intensity (in arbitrary units). [Reproduced with permission from ref. 64 (Copyright 2005, AAAS, www.sciencemag.org).]


  4. Fig. 4.

    Boron-containing BNCT agents. (a) 5-carboanyluracil. (b) Porphyrin-based polyhedral borane. [Reproduced from ref. 75 with permission of A. H. Soloway (Copyright 1998, American Chemical Society).]


Footnotes

  • To whom correspondence may be addressed. E-mail: pjena{at}vcu.edu or awc{at}psu.edu
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