Primary charge-recombination in an artificial photosynthetic reaction center

Kobori et al. 10.1073/pnas.0504598102.

Supporting Information

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Supporting Text
Supporting Figure 6
Supporting Figure 7
Supporting Figure 8

Supporting Figure 6

Fig. 6. Energy diagram (not scaled) and possible pathways of the singlet excitation energy transfers and the CS reactions in the triad.

Supporting Figure 7

Fig. 7. Time profiles of the relative populations for states of 1–6 in Fig. 6 calculated to reproduce the experimental results of Fig. 3 and the total quantum yield F_CS2 of the charge separation. F_CS2 = 0.4 is denoted by the red line (6) in which the population finally reaches to 0.4.

Supporting Figure 8

Fig. 8. Potential surfaces of the CS and one of the CR states (labeled with i) interacting by the electronic coupling V_CR,i.