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California Institute of Technology, MS 136-93, Pasadena, CA 91125
Contributed by Carver A. Mead, April 2, 1997
Standard results of electromagnetic theory are derived from the
direct interaction of macroscopic quantum systems; the only assumptions
used are the Einstein-deBroglie relations, the discrete nature of
charge, the Green's function for the vector potential, and the
continuity of the wave function. No reference is needed to Maxwell's
equations or to traditional quantum formalism. Correspondence limits
based on classical mechanics are shown to be inappropriate.
But the real glory of science is
that we can find a way of thinking such that the law is
evident. - R. P. Feynman
Foundations of Physics
Much has transpired since the first two decades of this century,
when the conceptual foundations for modern physics were put in place.
At that time, macroscopic mechanical systems were easily accessible and
well understood. The nature of electrical phenomena was mysterious;
experiments were difficult and their interpretation was murky. Today,
quite the reverse is true. Electrical experiments of breathtaking
clarity can be carried out, even in modestly equipped laboratories.
Electronic apparatus pervade virtually every abode and workplace.
Modern mechanical experiments rely heavily on electronic instrumentation. Yet, in spite of this reversal in the range of experience accessible to the average person, introductory treatments of
physics still use classical mechanics as a starting point.
Ernst Mach wrote (p. 596 in ref. 1), "The view that makes mechanics
the basis of the remaining branches of physics, and explains all
physical phenomena by mechanical ideas, is in our judgment a prejudice.
... The mechanical theory of nature, is, undoubtedly, in a
historical view, both intelligible and pardonable; and it may also, for
a time, have been of much value. But, upon the whole, it is an
artificial conception."
Classical mechanics is indeed inappropriate as a starting point for
physics because it is not fundamental; rather, it is the limit of an
incoherent aggregation of an enormous number of quantum elements. To
make contact with the fundamental nature of matter, we must work in a
coherent context where the quantum reality is preserved.
R. P. Feynman wrote (p. 15-8 in ref. 2), "There are many changes in
concepts that are important when we go from classical to quantum
mechanics. ... Instead of forces, we deal with the way interactions
change the wavelengths of waves."
Even Maxwell's equations have their roots in classical mechanics. They
were conceived as a theory of the ether: They express relations between
the magnetic field B and the electric field E,
which are defined in terms of the classical force F = q(E + v × B) on a
particle of charge q moving with velocity v. But
it is the vector potential A, rather than the magnetic field
B, that has a natural connection with the quantum nature of
matter Hamilton's formulation of classical mechanics was Although superconductivity was discovered in 1911, the
recognition that superconductors manifest quantum phenomena on a
macroscopic scale (4) came too late to play a role in the formulation
of quantum mechanics. Through modern experimental methods, however, superconducting structures give us direct access to the quantum nature
of matter. The superconducting state is a coherent state formed by the
collective interaction of a large fraction of the free electrons in a
material. Its properties are dominated by known and controllable
interactions within the collective ensemble. The dominant interaction
is collective because the properties of each electron depend on the
state of the entire ensemble, and it is electromagnetic because it
couples to the charges of the electrons. Nowhere in natural phenomena
do the basic laws of physics manifest themselves with more crystalline
clarity.
This paper is the first in a series in which we start at the
simplest possible conceptual level, and derive as many conclusions as
possible before moving to the next level of detail. In most cases,
understanding the higher level will allow us to see why the assumptions
of the level below were valid. In this stepwise fashion, we build up an
increasingly comprehensive understanding of the subject, always keeping
in view the assumptions required for any given result. We avoid
introducing concepts that we must "unlearn" as we progress. We
use as our starting point the magnetic interaction of macroscopic
quantum systems through the vector and scalar potentials
Model System
Our model system is a loop of superconducting wire Current is the flow of charge: I = dQ/dt. Each increment of charge dQ
carries an energy increment dW = V dQ into
the loop as it enters.
Proc. Natl. Acad. Sci. USA
Vol. 94,
pp. 6013-6018,
June 1997
Physics
as highlighted by Aharonov and Bohm (3).
and
remains
the starting point for the concepts underlying the quantum
theory. The correspondence principle would have every quantum system
approach the behavior of its classical-mechanics counterpart in the
limit where the mechanical action involved is large compared with
Planck's constant.
and V, which are the true
observable quantities. For clarity, the brief discussion given here is
limited to situations where the currents and voltages vary slowly; the four-vector generalization of these relations not only removes this
quasi-static limitation, but gives us electrostatics as well (5, 6).
the two ends
of the loop being colocated in space and either insulated or shorted,
depending on the experimental situation. Experimentally, the voltage
V between the two ends of the loop is related to the current
I flowing through the loop by
Two quantities are defined by this relationship:
[ 1 ]
, called the
magnetic flux*, and L, called the
inductance, which depends on the dimensions of the loop.
The total energy W stored in
the loop is thus
If we reduce the voltage to zero by, for example, connecting the
two ends of the loop to form a closed superconducting path, the current
I will continue to flow indefinitely: a persistent current.
If we open the loop and allow it to do work on an external circuit, we
can recover all the energy W.
[ 2 ]
If we examine closely the values of currents under a variety of
conditions, we find the full continuum of values for the quantities I, V, and
, except for persistent currents,
where only certain discrete values occur for any given loop (7, 8). By
experimenting with loops of different dimensions, we find the condition
that describes the values that occur experimentally:
|
[ 3 ] |
0 = 2.06783461 × 10
15 volt-second is called the flux
quantum or fluxoid; its value is accurate to a few parts in
109, independent of the detailed size, shape, or
composition of the superconductor forming the loop. We also find
experimentally that a rather large energy
sufficient to disrupt the
superconducting state entirely
is required to change the value of
n.
The more we reflect on Eq. 3, the more remarkable the result
appears. The quantities involved are the voltage and the magnetic flux.
These quantities are integrals of the quantities E and
B that appear in Maxwell's equations, and are therefore
usually associated with the electromagnetic field. Experimentally, we know that they can take on a continuum of values
except under special
conditions, when the arrangement of matter in the vicinity causes the
flux to take on precisely quantized values. In Maxwell's theory,
E and B represented the state of strain in a
mechanical medium (the ether) induced by electric charge. Einstein had
a markedly different view (p. 383 in ref. 9): "I feel that it is a
delusion to think of the electrons and the fields as two physically
different, independent entities. Since neither can exist without the
other, there is only one reality to be described, which
happens to have two different aspects; and the theory ought to
recognize this from the start instead of doing things twice." At the
most fundamental level, the essence of quantum mechanics lies in the
wave nature of matter. Einstein's view would suggest that
electromagnetic variables are related to the wave properties of the
electrons. Quantization is a familiar phenomenon in systems where the
boundary conditions give rise to standing waves. The quantization of
flux (Eq. 3) is a direct manifestation of the wave nature of
matter, expressed in electromagnetic variables.
Matter
To most nonspecialists, quantum mechanics is a baffling mixture of
waves, statistics, and arbitrary rules, ossified in a matrix of
impenetrable formalism. By using a superconductor, we can avoid the
statistics, the rules, and the formalism, and work directly with the
waves. The wave concept, accessible to intuition and common sense,
gives us "a way of thinking such that the law is evident."
Electrons in a superconductor are described by a wave function that has
an amplitude and a phase. The earliest treatment of the wave nature of
matter was the 1923 wave mechanics of deBroglie. He applied the 1905 Einstein postulate (W = 
) to the energy W of an electron wave, and identified the momentum
of an electron with the propagation vector of the
wave:
= 
. Planck's
constant h and its radian equivalent
= h/2
are necessary for merely historical reasons
when
our standard units were defined, it was not known that energy and
frequency were the same quantity.
The Einstein-deBroglie relations apply to the collective electrons in
a superconductor. The dynamics of the system can be derived from the
dispersion relation (10) between
and
. Both
and
are properties of the phase of the wave function and do not involve the amplitude, which, in collective systems, is
usually determined by some normalization condition. In a
superconductor, the constraint of charge neutrality is such a
condition.
The wave function must be continuous in space; at any given time, we
can follow the phase along a path from one end of the loop to the
other: the number of radians by which the phase advances as we traverse
the path is the phase accumulation
around the loop. If the phase at
one end of the loop changes relative to that at the other end, that
change must be reflected in the total phase accumulation around the
loop. The frequency
of the wave function at any point in space is
the rate at which the phase advances per unit time. If the frequency at
one end of the loop (
1) is the same as that at the other
end (
2), the phase difference between the two ends will
remain constant, and the phase accumulation will not change with time.
If the frequency at one end of the loop is higher than that at the
other, the phase accumulation will increase with time, and that change
must be reflected in the rate at which phase accumulates with the
distance l along the path. The rate at which phase around
the loop accumulates with time is the difference in frequency between
the two ends. The rate at which phase accumulates with distance
l is the component of the propagation vector
in the direction
along the path. Thus, the total phase accumulated around the loop is
|
[ 4 ] |
matching up means being equal modulo 2
. Thus,
for a wave that is confined to a closed loop, and has a single-valued,
continuous phase, the integral of Eq. 4 must be
n2
, where n is an integer. The large energy required to change n is evidence that the phase constraint
is a strong one
as long as the superconducting state stays intact, the
wave function remains intact as well.
These relations tell us that the magnetic flux and the propagation
vector will be quantized for a given loop; they do not tell us how the
frequency
in Eq. 4 is related to the potential V in Eq. 1. To make this connection, we must
introduce one additional assumption: The collective electron system
represented by the wave function is made up of elemental charges of
magnitude q0. By the Einstein relation, the
energy q0V of an elemental charge corresponds to a frequency
= q0V/
.
Electrodynamics
Electrodynamics is the interaction of matter via the
electromagnetic field. We can formulate our first relation between the electromagnetic quantities V and
and the phase
accumulation
of the wave function by comparing Eq. 1
with Eq. 4:
|
[ 5 ] |
0 = h/q0. We understand that the
potential V and the frequency
refer to differences in
these quantities between the two ends of the loop. Equivalently, we measure each of these quantities at one end of the loop using as a
reference the value at the other end of the loop. When we substitute
into Eq. 5 the measured value of
0 and the
known value of h, we obtain for q0 a
value that is exactly twice the charge qe of the
free electron. The usual explanation for this somewhat surprising
result is that each state in the superconductor is occupied by a pair
of electrons, rather than by an individual electron, so the elemental
charge q0 should be 2qe,
rather than qe. None of the conclusions that we
shall reach depends on the value of q0.
We have established the correspondence between the potential
V and the frequency 
the time integral of each
of these equivalent quantities in a closed loop is quantized. The line
integral of the propagation vector
around a closed
loop also is quantized. We would therefore suspect the existence of a
corresponding electromagnetic quantity, whose line integral is the
magnetic flux
. That quantity is the well-known vector potential
. The general relations among these
quantities, whether or not the loop is closed, are
|
[ 6 ] |
Coupling
Up to this point, we have tentatively identified the phase accumulation and the magnetic flux as two representations of the same physical entity. We assume that "winding up" the wave function with a voltage produces a propagation vector in the superconductor related to the motion of the electrons, and that this motion corresponds to a current because the electrons are charged. This viewpoint will allow us to understand the interaction between two coupled collective electron systems. We shall develop these relations in more detail when we study the current distribution within the wire itself.
Let us consider two identical loops of superconducting wire, the diameter of the wire being much smaller than the loop radius. We place an extremely thin insulator between the loops, which are superimposed on each other as closely as allowed by the insulator. In this configuration, both loops can be described, to an excellent approximation, by the same path in space, despite their being electrically distinct. As we experiment with this configuration, we make the following observations.
(i) When the two ends of the second loop are left open, its presence has no effect on the operation of the first loop. The relationship between a current flowing in the first loop and the voltage observed between the ends of the first loop follows Eq. 1, with exactly the same value of L as that observed when the second loop was absent.
(ii) The voltage observed between the two ends of the second loop under open conditions is almost exactly equal to that observed across the first loop.
(iii) When the second loop is shorted, the voltage observed across the first loop is nearly zero, independent of the current.
(iv) The current observed in the second loop under shorted conditions is nearly equal to that flowing in the first loop, but is of the opposite sign.
Similar measurements performed when the loops are separated allow us to observe how the coupling between the loops depends on their separation and relative orientation.
(v) For a given configuration, the voltage observed across the second loop remains proportional to the voltage across the first loop. The constant of proportionality, which is nearly unity when the loops are superimposed, decreases with the distance between the loops.
(vi) The constant of proportionality decreases as the axes of the two loops are inclined with respect to each other, goes to zero when the two loops are orthogonal, and reverses when one loop is flipped with respect to the other.
Observation i tells us that the presence of electrons in the second loop does not per se affect the operation of the first loop. The voltage across a loop is a direct manifestation of the phase accumulation around the loop. Observation ii tells us that current in a neighboring loop is as effective in producing phase accumulation in the wave function as is current in the same loop. The ability of current in one location to produce phase accumulation in the wave function of electrons in another location is called magnetic interaction. Observation vi tells us that the magnetic interaction is vectorial in nature. After making these and other similar measurements on many configurations, involving loops of different sizes and shapes, we arrive at the proper generalization of Eqs. 1 and 6:
|
|
[ 7 ] |
1 and
2 are taken along the first
and second loops, respectively. The quantity M, which by observation vi can be positive or negative depending on the
configuration, is called the mutual inductance; it is a measure of how
effective the current in one loop is at causing phase accumulation in
the other. When L1 = L2 = L, the magnitude of M can never exceed
L. Observations i-iv were obtained
under conditions where M
L. Experiments
evaluating the mutual coupling of loops of different sizes, shapes,
orientations, and spacings indicate that each element of wire of length
dl carrying the current
makes
a contribution to
that is proportional
to
, and to the inverse of the distance r from the current element to the point at which
is evaluated:
|
[ 8 ] |
as being the number of such wires per
unit area normal to the current flow. The 1/r form of the
integrand of Eq. 8 is called the Green's function; it tells
us how the vector potential is generated by currents everywhere in
space. It is perhaps more correct to say that the vector potential is a
bookkeeping device for evaluating the effect at a particular point of
all currents everywhere in space. Ernst Mach wrote (p. 317 in ref. 1),
"We cannot regard it as impossible that integral laws
... will some day take the place of the ... differential laws
that now make up the science of mechanics. ... In such an event, the
concept of force will have become superfluous." Eqs. 6 and 8 and are the fundamental integral laws for
collective electromagnetic interaction. The equivalent differential
equation is
2
=
µ0
(5, 6).
We can express Eq. 2 in a way that gives us additional insight into the energy stored in the coil:
|
[ 9 ] |
;
it is not limited to the
from the
current in the coil itself. The integrals in Eq. 9 involve the entire coil. From them we can take a conceptual step and, using our
visualization of the current density, imagine an energy density
·
ascribed to every point in space:
|
[ 10 ] |
Electrodynamic Momentum
Feynman commented on the irrelevance of the concept of force in a
quantum context. At the fundamental level, we can understand the
behavior of a quantum system using only the wave properties of matter.
But we experience forces between currents in every encounter with
electric motors, relays, and other electromagnetic actuators. How do
these forces arise from the underlying quantum reality? We can make a
connection between the classical concept of force and the quantum
nature of matter through the concept of momentum. Using the deBroglie
postulate relating the momentum
of an electron to
the propagation vector
of the wave function, and
identifying the two integrands in Eq. 6, the electrodynamic momentum of an elemental charge is
|
[ 11 ] |
|
[ 12 ] |
q
of each
electron, we have a canceling +q
from one
of the background positive charges. The electric field that accelerates
electrons in one direction exerts an equal force in the opposite
direction on the background positive charges. We have, however, just
encountered our first big surprise: We recognize the second form of Eq. 12, which came from Newton's law, as the integral form of
one of Maxwell's equations!
We would expect the total momentum P of the collective
electron system to be the momentum per charge times the number of
charges in the loop. If there are
charges per unit length of wire
that take part in the motion, integrating Eq. 11 along the
loop gives
|
[ 13 ] |
charges per unit
length moving at velocity v; therefore, I =
q0v, and Eq. 13
becomes
|
[ 14 ] |
Forces on Currents
In our experiments on coupled loops, we have already seen how the
current in one loop induces phase accumulation in another loop; the
relations involved were captured in Eq. 7. In any situation where we change the coupling of collective systems by changing the
spatial arrangement, mechanical work may be involved. Our model system
for studying this interaction consists of two identical shorted loops
of individual inductance L0, each carrying a
persistent flux
. As long as the superconducting state retains its
integrity, the cyclic constraint on the wave function guarantees that
the flux
in each loop will be constant, independent of the coupling between loops. Because M enters symmetrically in Eq. 7, the current I will be the same in both loops.
Hence, L0 and
will remain constant, whereas
M and I will be functions of the spatial
arrangement of the loops
M will be large and positive when
the loops are brought together with their currents flowing in the same
direction, and will be large and negative when the loops are brought
together with their currents flowing in opposite directions. From Eq. 7,
= (L0 + M)I. Substituting
into Eq. 9, and
noting that the total energy of the system is twice that for a single
coil,
|
[ 15 ] |
|
[ 16 ] |
whose currents are circulating in the same direction
are moved closer. It is well known
that electric charges of the same sign repel each other. We might
expect the current, being the spatial analog of the charge, to behave
in a similar manner. However, Eq. 15 indicates that the total energy of the system decreases as M increases. How
does this attractive interaction of currents circulating in the same direction come about?
The electron velocity is proportional to I. As M
is increased, the electrons in both loops slow down because they have
more inertia due to the coupling with electrons in the other loop. This
effect is evident in Eq. 15, where I =
/(L0 + M). Thus, there are two
competing effects: the decrease in energy due to the lower velocity,
and the increase in energy due to the increase in inertia of each
electron. The energy goes as the square of the velocity, but goes only
linearly with the inertia, so the velocity wins. The net effect is a
decrease in energy as currents in the same direction are coupled, and
hence an attractive force. We can see how the classical force law
discovered in 1823 by Ampère arises naturally from the collective
quantum behavior, which determines not only the magnitude, but also the
sign, of the effect.
Multiturn Coils
The interaction in a collective system scales as the square of the number of electrons moving in concert. Thus, we might expect the quantum scaling laws to be most clearly manifest in the properties of closely coupled multiturn coils, where the number of electrons is proportional to the number of turns. We can construct an N-turn coil by connecting in series N identical, closely coupled loops. In this arrangement, the current through all loops is equal to the current I through the coil, and the voltage V across the coil is equal to the sum of the individual voltages across the loops. If A0 is the vector potential from the current in one loop, we expect the vector potential from N loops to be N A0, because the current in each loop contributes. The flux integral is taken around N turns, so the path is N times the length l0 of a single turn. The total flux integral is thus
|
[ 17 ] |
where the granularity of
the flux due to
is as small as might be required by any
correspondence procedure. Thus, it is clear that collective quantum
systems do not have a classical correspondence limit.
Total Momentum
To see why our simplistic approach has taken us so far, we must
understand the current distribution within the superconductor itself.
We saw that the vector potential made a contribution to the momentum of
each electron, which we called the electrodynamic momentum:
el = q
. The
mass m of an electron moving with velocity
also contributes to the electron's momentum:
mv = m
. The total
momentum is the sum of these two contributions:
|
[ 18 ] |
= (
q0
)/m
is thus a direct measure of the imbalance between the total momentum

and the electrodynamic momentum
q0
. When these
two quantities are matched, the velocity is zero. The current density
is just the motion of
elementary charges per unit volume:
= q0 
. We can thus express
Eq. 18 in terms of the wave vector
,
the vector potential
, and the current
density
:
|
[ 19 ] |
Current Distribution
We are now in a position to investigate how current distributes
itself inside a superconductor. If
were
constant throughout the wire, the motion of the electrons would be
determined by the common wave vector
of the
collective electron system, and we would expect the persistent current
for a given flux to be proportional to the cross-sectional area of the
wire, and thus the inductance L of a loop of wire to be
inversely related to the wire cross section. When we perform
experiments on loops of wire that have identical paths in space,
however, we find that the inductance is only a weak function of the
wire diameter, indicating that the current is not uniform across the
wire, and therefore that
is far from
constant. If we make a loop of superconducting tubing, instead of wire,
we find that it has exactly the same inductance as does a loop made
with wire of the same diameter, indicating that current is flowing at
the surface of the loop, but is not flowing throughout the bulk.
Before taking on the distribution of current in a wire, we can examine
a simpler example. In a simply connected bulk superconductor, the
single-valued nature of the wave function can be satisfied only if the
phase is everywhere the same:
= 0. Any phase
accumulation induced through the
vector
created by an external current will be canceled by a screening current
density
in the opposite direction, as we
saw in observations iii and iv. To make the
problem tractable, we consider a situation where a vector potential
A0 at the surface of a bulk superconducting slab
is created by distant currents parallel to the surface of the slab. The
current distribution perpendicular to the surface is a highly localized
phenomenon, so it is most convenient to use the differential
formulation of Eq. 8. We suppose that conditions are the
same at all points on the surface, and therefore that A
changes in only the x direction, perpendicular to the
surface, implying that
2A =
2A/
x2.
|
[ 20 ] |
|
[ 21 ] |
, the screening distance, penetration depth, or skin
depth. For a typical superconductor,
is of the order of
1028/m3, so
should be a few tens of
nanometers. Experimentally, simple superconductors have
50 nanometers
many orders of magnitude smaller than the macroscopic wire
thickness that we are using.
Current in a Wire
At long last, we can visualize the current distribution within the
superconducting wire itself. Because the skin depth is so small, the
surface of the wire appears flat on that scale, and we can use the
solution for a flat surface. The current will be a maximum at the
surface of the wire, and will die off exponentially with distance into
the interior of the wire. We can appreciate the relations involved by
examining a simple example. A 10-cm-diameter loop of 0.1-mm-diameter
wire has an inductance of 4.4 × 10
7 Henry (p. 193 in ref. 11): A persistent current of 1 Ampere in this loop produces a
flux of 4.4 × 10
7 volt-second, which is 2.1 × 108 flux quanta. The electron wave function thus has a
total phase accumulation of 2.1 × 108 cycles along
the length of the wire, corresponding to a wave vector
k = 4.25 × 109 m
1. Due
to the cyclic constraint on the wave function, this phase accumulation
is shared by all electrons in the wire, whether or not they are
carrying current.
In the region where current is flowing, the moving mass of the
electrons contributes to the total phase accumulation. The 1-Ampere of
current results from a current density of 6.4 × 1010
Amperes per square meter flowing in a thin "skin" 
thick,
just inside the surface. This current density is the result of the 1028 electrons per cubic meter moving with a velocity of
v
20 meters per second. The mass of the electron
moving at this velocity contributes mv/
= 1.7 × 105 m
1 to the total wave vector of the wave
function, which is less than one part in 104 of that
contributed by the vector potential. That small difference, existing in
about 1 part in 106 of the cross-sectional area, is enough
to bring
and
into balance in the interior of the wire.
In the interior of the wire, the propagation vector of the wave
function is matched to the vector potential, and the current is
therefore zero. As we approach the surface, A decreases
slightly, and the difference between k and
Aq0/
is manifest as a current. At the
surface, the value and radial slope of A inside and outside the wire match, and the value of A is still within one part
in 104 of that in the center of the wire. So our simplistic
view
that the vector potential and the wave vector were two
representations of the same quantity
is precisely true in the center
of the wire, and is nearly true even at the surface. The current
is not the propagation vector
of
the wave, but, for a fixed configuration,
is
proportional to
by Eqs. 8 and 19. For that reason, we were able to deduce the
electromagnetic laws relating current and voltage from the quantum
relations between wave vector and frequency.
Conclusion
We took to heart Einstein's belief that the electrons and the fields were two aspects of the same reality, and were able to treat the macroscopic quantum system and the electromagnetic field as elements of a unified subject. We heeded Mach's advice that classical mechanics was not the place to start, followed Feynman's directive that interactions change the wavelengths of waves, and saw that there is a correspondence limit more appropriate than the classical-mechanics version used in traditional introductions to quantum theory. We found Newton's law masquerading as one of Maxwell's equations. We were able to derive a number of important results using only the simplest properties of waves, the Einstein postulate relating frequency to energy, the deBroglie postulate relating momentum to wave vector, and the discrete charge of the electron. It thus appears possible to formulate a unified, conceptually correct introduction to both the quantum nature of matter and the fundamental laws of electromagnetic interaction without using either Maxwell's equations or standard quantum formalism.
We use this relation to define the voltage
V.
I am indebted to Richard F. Lyon, Sanjoy Mahajan, William B. Bridges, Rahul Sarpeshkar, Richard Neville, and Lyn Dupré for helpful discussion and critique of the material, and to Calvin Jackson for his help in preparing the manuscript. The work was supported by the Arnold and Mabel Beckman Foundation, and by Gordon and Betty Moore.
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