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Published online on February 4, 2000, 10.1073/pnas.030264697
PNAS | February 15, 2000 | vol. 97 | no. 4 | 1380-1384


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Vol. 97, Issue 4, 1380-1384, February 15, 2000

Chemistry
 Archimedean solids: Transition metal mediated rational self-assembly of supramolecular-truncated tetrahedra

Stefan Leininger, Jun Fan, Marion Schmitz, and Peter J. Stang*

Department of Chemistry, University of Utah, Salt Lake City, UT 84112

Edited by George M. Whitesides, Harvard University, Cambridge, MA, and approved December 6, 1999 (received for review June 24, 1999)

A family of nanoscale-sized supramolecular cage compounds with a polyhedral framework is prepared by self-assembly from tritopic building blocks and rectangular corner units via noncovalent coordination interactions. These highly symmetrical cage compounds are described as face-directed, self-assembled truncated tetrahedra with Td symmetry.

* To whom reprint requests should be addressed. E-mail: stang{at}chemistry.utah.edu.


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