Symmetry in chemistry from the hydrogen atom to proteins

  1. Michael E. Kellman*
  1. Department of Chemistry, University of Oregon, Eugene, OR 97403
  1. Figure 1

    Equilibrium rigid structure of water molecule H2O with point group C2v.


  2. Figure 2

    Elliptical Kepler orbit of electron around the nucleus in the hydrogen atom. Runge-Lenz vector is a conserved quantity.


  3. Figure 3

    (a) Literal depiction of molecular model of the two-electron atom. (b) More realistic depiction, with the linear molecular structure a “blob” of charge surrounding the nucleus.


  4. Figure 4

    Precessing perihelion of an orbit that conserves angular momentum but not the Runge-Lenz vector.


  5. Figure 5

    Heuristic picture of electron correlation in which the most favorable configuration maximizes the difference B⃗ = A⃗ 1A⃗ 2 of Runge-Lenz vectors.


  6. Figure 6

    Supermultiplet rotor-vibrator molecular classification of doubly excited states of He with both electrons excited to n = 3 shell, from ref. 4.


Footnotes

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