Induced-fit recognition of DNA by organometallic complexes with dynamic stereogenic centers






Supporting Figure 17

Fig. 17. Variation in the 1H NMR chemical shift of ethyl CH3 protons of aqua diastereomers 2Aw (RRu*RN*) and 2Bw (SRu*RN*) of [(h6-Bip)Ru(H2O)(Et-en)]2+ (6 mM Ru in 10% D2O/90%H2O) as a function of pH. The curves are computer-fits giving pKa (H2O) of 7.57 (± 0.01) for 2Aw and 7.35 (± 0.01) for 2Bw.

This Article

  1. Published online before print December 1, 2003, doi: 10.1073/pnas.2434016100 PNAS December 9, 2003 vol. 100 no. 25 14623-14628
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