Adaptations of guest and host in expanded self-assembled capsules

Ajami and Rebek. 10.1073/pnas.0707759104.

Supporting Information

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SI Figure 10
SI Figure 11
SI Figure 12
SI Figure 13
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SI Figure 19
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SI Figure 21
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SI Figure 10

Fig. 10. ¹H-NMR spectra (600 MHz, mesitylene-d₁₂) of encapsulated p-ethyl, propyl, butyl benzene in 1.2₄.1.

SI Figure 11

Fig. 11. Upfield shift of aromatic hydrogen of p-ethyl, propyl, butyl benzene in 1.2₄.1.

SI Figure 12

Fig. 12. ¹H-NMR spectra (600 MHz, mesitylene-d₁₂) of encapsulated (2-chloro ethyl)benzene and (3-chloro propyl) benzene in 1.2₄.1.

SI Figure 13

Fig. 13. ¹H-NMR spectra (600 MHz, mesitylene-d₁₂) of encapsulated N,N-dimethyl-p-toluidine in 1.2₄.1.

SI Figure 14

Fig. 14. ¹H-NMR spectra (600 MHz, mesitylene-d₁₂) of encapsulated arachidonic acid in 1.2₈.1.

SI Figure 15

Fig. 15. ¹H-NMR spectra (600 MHz, mesitylene-d₁₂) of encapsulated arachidonic acid ethyl ester in 1.2₈.1.

SI Figure 16

Fig. 16. ¹H-NMR spectra (600 MHz, mesitylene-d₁₂) of encapsulated arachidonoyl cyclopropylamide in 1.2₈.1.

SI Figure 17

Fig. 17. ¹H-NMR spectra (600 MHz, mesitylene-d₁₂) of encapsulated anadamide in 1.2₈.1.

SI Figure 18

Fig. 18. ¹H-NMR spectra (600 MHz, mesitylene-d₁₂) of encapsulated docosahexaenoic acid methyl ester in 1.2₈.1.

SI Figure 19

Fig. 19. ¹H-NMR spectra (600 MHz, mesitylene-d₁₂) of encapsulated palmitonyl ethanolamide in 1.2₈.1.

SI Figure 20

Fig. 20. ¹H-NMR spectra (600 MHz, mesitylene-d₁₂) of encapsulated 9-octadecenamide in 1.2₈.1.

SI Figure 21

Fig. 21. ¹H-NMR spectra (600 MHz, mesitylene-d₁₂) of encapsulated oleic acid ethyl ester in 1.2₈.1.

SI Figure 22

Fig. 22. ¹H-NMR spectra (600 MHz, mesitylene-d₁₂) of encapsulated 13-docosenamide in 1.2₈.1.

SI Figure 23

Fig. 23. ¹H-NMR spectra (600 MHz, mesitylene-d₁₂) of encapsulated capsaicin in 1.2₄.1.

SI Figure 24

Fig. 24. (a) ¹H-NMR spectra (600 MHz, mesitylene-d₁₂) of encapsulated oleic acid ethyl ester in 1.2₈.1. (b) Addition of 5 ml of methanol d₄ to a. (c) Addition of 5 ml of methanol d₄ to b. (d) Addition of 5 ml of methanol d₄ to c. (e) Addition of 5 ml of methanol d₄ to d.