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Research Article

Evidence for deposition of 10 million tonnes of impact spherules across four continents 12,800 y ago

James H. Wittke, James C. Weaver, Ted E. Bunch, James P. Kennett, Douglas J. Kennett, Andrew M. T. Moore, Gordon C. Hillman, Kenneth B. Tankersley, Albert C. Goodyear, Christopher R. Moore, I. Randolph Daniel Jr., Jack H. Ray, Neal H. Lopinot, David Ferraro, Isabel Israde-Alcántara, James L. Bischoff, Paul S. DeCarli, Robert E. Hermes, Johan B. Kloosterman, Zsolt Revay, George A. Howard, David R. Kimbel, Gunther Kletetschka, Ladislav Nabelek, Carl P. Lipo, Sachiko Sakai, Allen West, and Richard B. Firestone
  1. aGeology Program, School of Earth Science and Environmental Sustainability, Northern Arizona University, Flagstaff, AZ 86011;
  2. bWyss Institute for Biologically Inspired Engineering, Harvard University, Cambridge, MA 02138;
  3. cDepartment of Earth Science and Marine Science Institute, University of California, Santa Barbara, CA 93106;
  4. dDepartment of Anthropology, Pennsylvania State University, University Park, PA 16802;
  5. eCollege of Liberal Arts, Rochester Institute of Technology, Rochester, NY 14623;
  6. fInstitute of Archaeology, University College London, London WC1H0PY, United Kingdom;
  7. gDepartments of Anthropology and Geology, University of Cincinnati, Cincinnati, OH 45221;
  8. hSouth Carolina Institute of Archaeology and Anthropology, University of South Carolina, Columbia, SC 29208;
  9. iSavannah River Archaeological Research Program, South Carolina Institute of Archaeology and Anthropology, University of South Carolina, New Ellenton, SC 29809;
  10. jDepartment of Anthropology, East Carolina University, Greenville, NC 27858;
  11. kCenter for Archaeological Research, Missouri State University, Springfield, MO 65897;
  12. lViejo California Associates, Joshua Tree, CA 92252;
  13. mDepartamento de Geología y Mineralogía, Edificio U4, Instituto de Investigaciones Metalúrgicas, Universidad Michoacana de San Nicólas de Hidalgo, C. P. 58060, Morelia, Michoacán, México;
  14. nUS Geological Survey, Menlo Park, CA 94025;
  15. oSRI International, Menlo Park, CA 94025;
  16. pLos Alamos National Laboratory, Los Alamos, NM 87545;
  17. qExploration Geologist, 1016 NN, Amsterdam, The Netherlands;
  18. rForschungsneutronenquelle Heinz Maier-Leibnitz, Technische Universität München, 85748 Garching, Germany;
  19. sRestoration Systems, LLC, Raleigh, NC 27604;
  20. tKimstar Research, Fayetteville, NC 28312;
  21. uFaculty of Science, Charles University in Prague, 12843 Prague, Czech Republic;
  22. vInstitute of Geology, Academy of Sciences of the Czech Republic, Public Research Institute, 16500 Prague, Czech Republic;
  23. wInstitute for Integrated Research in Materials, Environments, and Society, California State University, Long Beach, CA 90840;
  24. xGeoScience Consulting, Dewey, AZ 86327; and
  25. yLawrence Berkeley National Laboratory, Berkeley, CA 94720

See allHide authors and affiliations

PNAS June 4, 2013 110 (23) E2088-E2097; https://doi.org/10.1073/pnas.1301760110
James H. Wittke
aGeology Program, School of Earth Science and Environmental Sustainability, Northern Arizona University, Flagstaff, AZ 86011;
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James C. Weaver
bWyss Institute for Biologically Inspired Engineering, Harvard University, Cambridge, MA 02138;
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Ted E. Bunch
aGeology Program, School of Earth Science and Environmental Sustainability, Northern Arizona University, Flagstaff, AZ 86011;
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  • For correspondence: tbear1@cableone.net
James P. Kennett
cDepartment of Earth Science and Marine Science Institute, University of California, Santa Barbara, CA 93106;
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Douglas J. Kennett
dDepartment of Anthropology, Pennsylvania State University, University Park, PA 16802;
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Andrew M. T. Moore
eCollege of Liberal Arts, Rochester Institute of Technology, Rochester, NY 14623;
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Gordon C. Hillman
fInstitute of Archaeology, University College London, London WC1H0PY, United Kingdom;
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Kenneth B. Tankersley
gDepartments of Anthropology and Geology, University of Cincinnati, Cincinnati, OH 45221;
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Albert C. Goodyear
hSouth Carolina Institute of Archaeology and Anthropology, University of South Carolina, Columbia, SC 29208;
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Christopher R. Moore
iSavannah River Archaeological Research Program, South Carolina Institute of Archaeology and Anthropology, University of South Carolina, New Ellenton, SC 29809;
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I. Randolph Daniel Jr.
jDepartment of Anthropology, East Carolina University, Greenville, NC 27858;
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Jack H. Ray
kCenter for Archaeological Research, Missouri State University, Springfield, MO 65897;
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Neal H. Lopinot
kCenter for Archaeological Research, Missouri State University, Springfield, MO 65897;
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David Ferraro
lViejo California Associates, Joshua Tree, CA 92252;
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Isabel Israde-Alcántara
mDepartamento de Geología y Mineralogía, Edificio U4, Instituto de Investigaciones Metalúrgicas, Universidad Michoacana de San Nicólas de Hidalgo, C. P. 58060, Morelia, Michoacán, México;
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James L. Bischoff
nUS Geological Survey, Menlo Park, CA 94025;
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Paul S. DeCarli
oSRI International, Menlo Park, CA 94025;
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Robert E. Hermes
pLos Alamos National Laboratory, Los Alamos, NM 87545;
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Johan B. Kloosterman
qExploration Geologist, 1016 NN, Amsterdam, The Netherlands;
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Zsolt Revay
rForschungsneutronenquelle Heinz Maier-Leibnitz, Technische Universität München, 85748 Garching, Germany;
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George A. Howard
sRestoration Systems, LLC, Raleigh, NC 27604;
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David R. Kimbel
tKimstar Research, Fayetteville, NC 28312;
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Gunther Kletetschka
uFaculty of Science, Charles University in Prague, 12843 Prague, Czech Republic;
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Ladislav Nabelek
uFaculty of Science, Charles University in Prague, 12843 Prague, Czech Republic;
vInstitute of Geology, Academy of Sciences of the Czech Republic, Public Research Institute, 16500 Prague, Czech Republic;
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Carl P. Lipo
wInstitute for Integrated Research in Materials, Environments, and Society, California State University, Long Beach, CA 90840;
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Sachiko Sakai
wInstitute for Integrated Research in Materials, Environments, and Society, California State University, Long Beach, CA 90840;
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Allen West
xGeoScience Consulting, Dewey, AZ 86327; and
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Richard B. Firestone
yLawrence Berkeley National Laboratory, Berkeley, CA 94720
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  1. Edited* by Steven M. Stanley, University of Hawaii, Honolulu, HI, and approved April 9, 2013 (received for review January 28, 2013)

This article has Letters. Please see:

  • Relationship between Research Article and Letter - October 02, 2013
  • Relationship between Research Article and Letter - September 17, 2013
  • Relationship between Research Article and Letter - October 29, 2013
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Significance

We present detailed geochemical and morphological analyses of nearly 700 spherules from 18 sites in support of a major cosmic impact at the onset of the Younger Dryas episode (12.8 ka). The impact distributed ∼10 million tonnes of melted spherules over 50 million square kilometers on four continents. Origins of the spherules by volcanism, anthropogenesis, authigenesis, lightning, and meteoritic ablation are rejected on geochemical and morphological grounds. The spherules closely resemble known impact materials derived from surficial sediments melted at temperatures >2,200 °C. The spherules correlate with abundances of associated melt-glass, nanodiamonds, carbon spherules, aciniform carbon, charcoal, and iridium.

Abstract

Airbursts/impacts by a fragmented comet or asteroid have been proposed at the Younger Dryas onset (12.80 ± 0.15 ka) based on identification of an assemblage of impact-related proxies, including microspherules, nanodiamonds, and iridium. Distributed across four continents at the Younger Dryas boundary (YDB), spherule peaks have been independently confirmed in eight studies, but unconfirmed in two others, resulting in continued dispute about their occurrence, distribution, and origin. To further address this dispute and better identify YDB spherules, we present results from one of the largest spherule investigations ever undertaken regarding spherule geochemistry, morphologies, origins, and processes of formation. We investigated 18 sites across North America, Europe, and the Middle East, performing nearly 700 analyses on spherules using energy dispersive X-ray spectroscopy for geochemical analyses and scanning electron microscopy for surface microstructural characterization. Twelve locations rank among the world’s premier end-Pleistocene archaeological sites, where the YDB marks a hiatus in human occupation or major changes in site use. Our results are consistent with melting of sediments to temperatures >2,200 °C by the thermal radiation and air shocks produced by passage of an extraterrestrial object through the atmosphere; they are inconsistent with volcanic, cosmic, anthropogenic, lightning, or authigenic sources. We also produced spherules from wood in the laboratory at >1,730 °C, indicating that impact-related incineration of biomass may have contributed to spherule production. At 12.8 ka, an estimated 10 million tonnes of spherules were distributed across ∼50 million square kilometers, similar to well-known impact strewnfields and consistent with a major cosmic impact event.

  • Clovis–Folsom
  • lechatelierite
  • tektite
  • wildfires

Footnotes

  • ↵1To whom correspondence should be addressed. E-mail: tbear1{at}cableone.net.
  • ↵2Retired.

  • Author contributions: J.H.W., J.C.W., T.E.B., J.P.K., D.J.K., A.M.T.M., G.C.H., K.B.T., A.C.G., D.F., I.I.-A., R.E.H., J.B.K., Z.R., D.R.K., G.K., C.P.L., S.S., A.W., and R.B.F. designed research; J.H.W., J.C.W., T.E.B., J.P.K., D.J.K., A.M.T.M., G.C.H., K.B.T., A.C.G., C.R.M., I.R.D., J.H.R., N.H.L., D.F., I.I.-A., J.L.B., P.S.D., R.E.H., J.B.K., Z.R., G.A.H., D.R.K., G.K., L.N., C.P.L., S.S., A.W., and R.B.F. performed research; J.H.W., J.C.W., T.E.B., J.P.K., D.J.K., A.M.T.M., K.B.T., A.C.G., D.F., I.I.-A., P.S.D., R.E.H., J.B.K., Z.R., G.K., L.N., C.P.L., S.S., A.W., and R.B.F. analyzed data; and J.H.W., J.C.W., T.E.B., J.P.K., D.J.K., A.M.T.M., K.B.T., A.C.G., C.R.M., I.R.D., J.H.R., N.H.L., D.F., I.I.-A., J.L.B., P.S.D., R.E.H., J.B.K., G.A.H., D.R.K., G.K., A.W., and R.B.F. wrote the paper.

  • The authors declare no conflict of interest.

  • ↵*This Direct Submission article had a prearranged editor.

  • This article contains supporting information online at www.pnas.org/lookup/suppl/doi:10.1073/pnas.1301760110/-/DCSupplemental.

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Ten million tonnes of impact spherules at 12.8 ka
James H. Wittke, James C. Weaver, Ted E. Bunch, James P. Kennett, Douglas J. Kennett, Andrew M. T. Moore, Gordon C. Hillman, Kenneth B. Tankersley, Albert C. Goodyear, Christopher R. Moore, I. Randolph Daniel, Jack H. Ray, Neal H. Lopinot, David Ferraro, Isabel Israde-Alcántara, James L. Bischoff, Paul S. DeCarli, Robert E. Hermes, Johan B. Kloosterman, Zsolt Revay, George A. Howard, David R. Kimbel, Gunther Kletetschka, Ladislav Nabelek, Carl P. Lipo, Sachiko Sakai, Allen West, Richard B. Firestone
Proceedings of the National Academy of Sciences Jun 2013, 110 (23) E2088-E2097; DOI: 10.1073/pnas.1301760110

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Ten million tonnes of impact spherules at 12.8 ka
James H. Wittke, James C. Weaver, Ted E. Bunch, James P. Kennett, Douglas J. Kennett, Andrew M. T. Moore, Gordon C. Hillman, Kenneth B. Tankersley, Albert C. Goodyear, Christopher R. Moore, I. Randolph Daniel, Jack H. Ray, Neal H. Lopinot, David Ferraro, Isabel Israde-Alcántara, James L. Bischoff, Paul S. DeCarli, Robert E. Hermes, Johan B. Kloosterman, Zsolt Revay, George A. Howard, David R. Kimbel, Gunther Kletetschka, Ladislav Nabelek, Carl P. Lipo, Sachiko Sakai, Allen West, Richard B. Firestone
Proceedings of the National Academy of Sciences Jun 2013, 110 (23) E2088-E2097; DOI: 10.1073/pnas.1301760110
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