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Research Article

Chiral heliconical ground state of nanoscale pitch in a nematic liquid crystal of achiral molecular dimers

Dong Chen, Jan H. Porada, Justin B. Hooper, Arthur Klittnick, Yongqiang Shen, Michael R. Tuchband, Eva Korblova, Dmitry Bedrov, David M. Walba, Matthew A. Glaser, Joseph E. Maclennan, and Noel A. Clark
PNAS October 1, 2013 110 (40) 15931-15936; https://doi.org/10.1073/pnas.1314654110
Dong Chen
aDepartment of Physics and Liquid Crystal Materials Research Center, University of Colorado Boulder, Boulder, CO 80309-0390;
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Jan H. Porada
bDepartment of Chemistry and Biochemistry and Liquid Crystal Materials Research Center, University of Colorado Boulder, Boulder, CO 80309-0215;
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Justin B. Hooper
cDepartment of Materials Science and Engineering, The University of Utah, Salt Lake City, UT 84112; and
dLiquid Crystal Materials Research Center, University of Colorado Boulder, Boulder, CO 80309-0390
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Arthur Klittnick
aDepartment of Physics and Liquid Crystal Materials Research Center, University of Colorado Boulder, Boulder, CO 80309-0390;
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Yongqiang Shen
aDepartment of Physics and Liquid Crystal Materials Research Center, University of Colorado Boulder, Boulder, CO 80309-0390;
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Michael R. Tuchband
aDepartment of Physics and Liquid Crystal Materials Research Center, University of Colorado Boulder, Boulder, CO 80309-0390;
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Eva Korblova
bDepartment of Chemistry and Biochemistry and Liquid Crystal Materials Research Center, University of Colorado Boulder, Boulder, CO 80309-0215;
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Dmitry Bedrov
cDepartment of Materials Science and Engineering, The University of Utah, Salt Lake City, UT 84112; and
dLiquid Crystal Materials Research Center, University of Colorado Boulder, Boulder, CO 80309-0390
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David M. Walba
bDepartment of Chemistry and Biochemistry and Liquid Crystal Materials Research Center, University of Colorado Boulder, Boulder, CO 80309-0215;
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Matthew A. Glaser
aDepartment of Physics and Liquid Crystal Materials Research Center, University of Colorado Boulder, Boulder, CO 80309-0390;
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Joseph E. Maclennan
aDepartment of Physics and Liquid Crystal Materials Research Center, University of Colorado Boulder, Boulder, CO 80309-0390;
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Noel A. Clark
aDepartment of Physics and Liquid Crystal Materials Research Center, University of Colorado Boulder, Boulder, CO 80309-0390;
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  • For correspondence: noel.clark@colorado.edu
  1. Contributed by Noel A. Clark, August 8, 2013 (sent for review July 10, 2013)

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  • Twist–bend nematic phase of achiral dimers
    - Sep 19, 2013
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Article Information

vol. 110 no. 40 15931-15936
DOI: 
https://doi.org/10.1073/pnas.1314654110
PubMed: 
24006362

Published By: 
National Academy of Sciences
Print ISSN: 
0027-8424
Online ISSN: 
1091-6490
History: 
  • Published in issue October 1, 2013.
  • Published first September 4, 2013.

Copyright & Usage: 
Freely available online through the PNAS open access option.

Author Information

  1. Dong Chena,
  2. Jan H. Poradab,
  3. Justin B. Hooperc,d,
  4. Arthur Klittnicka,
  5. Yongqiang Shena,
  6. Michael R. Tuchbanda,
  7. Eva Korblovab,
  8. Dmitry Bedrovc,d,
  9. David M. Walbab,
  10. Matthew A. Glasera,
  11. Joseph E. Maclennana, and
  12. Noel A. Clarka,1
  1. aDepartment of Physics and Liquid Crystal Materials Research Center, University of Colorado Boulder, Boulder, CO 80309-0390;
  2. bDepartment of Chemistry and Biochemistry and Liquid Crystal Materials Research Center, University of Colorado Boulder, Boulder, CO 80309-0215;
  3. cDepartment of Materials Science and Engineering, The University of Utah, Salt Lake City, UT 84112; and
  4. dLiquid Crystal Materials Research Center, University of Colorado Boulder, Boulder, CO 80309-0390
  1. Contributed by Noel A. Clark, August 8, 2013 (sent for review July 10, 2013)

Footnotes

  • ↵1To whom correspondence should be addressed. E-mail: noel.clark{at}colorado.edu.
  • Author contributions: D.C., J.H.P., J.B.H., A.K., Y.S., M.R.T., E.K., D.B., D.M.W., M.A.G., and N.A.C. designed research; D.C., J.H.P., J.B.H., A.K., Y.S., M.R.T., E.K., M.A.G., and N.A.C. performed research; J.H.P. and E.K. contributed new reagents/analytic tools; D.C., J.H.P., J.B.H., A.K., Y.S., M.R.T., D.B., D.M.W., M.A.G., J.E.M., and N.A.C. analyzed data; and D.C., J.H.P., D.B., J.E.M., and N.A.C. wrote the paper.

  • The authors declare no conflict of interest.

  • See Commentary on page 15855.

  • This article contains supporting information online at www.pnas.org/lookup/suppl/doi:10.1073/pnas.1314654110/-/DCSupplemental.

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Article usage

Article usage: September 2013 to January 2021

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Sep 201327977169
Oct 20133400106240
Nov 201343523123
Dec 20132041347
Total 20136836149579
Jan 20142053284
Feb 20141782966
Mar 20141823362
Apr 20141611868
May 20141282937
Jun 2014882326
Jul 20141402453
Aug 20141165883
Sep 20141525044
Oct 20142064354
Nov 20141013131
Dec 2014931433
Total 20141750384641
Jan 201591916
Feb 20151061932
Mar 20151172023
Apr 2015891662
May 2015981544
Jun 201596935
Jul 201580843
Aug 2015781030
Sep 2015882152
Oct 2015861641
Nov 2015722649
Dec 2015651126
Total 20151066180453
Jan 2016681754
Feb 2016661425
Mar 2016583129
Apr 2016531117
May 2016491430
Jun 2016601627
Jul 201673829
Aug 2016831128
Sep 2016744836
Oct 2016678731
Nov 20168013731
Dec 20166690112
Total 2016797484449
Jan 2017674826
Feb 2017537321
Mar 2017752336
Apr 2017471440
May 2017641930
Jun 2017543933
Jul 2017471646
Aug 2017541736
Sep 2017571524
Oct 2017441929
Nov 2017992138
Dec 2017541827
Total 2017715322386
Jan 2018621120
Feb 2018423435
Mar 2018484328
Apr 2018655328
May 2018453714
Jun 2018514216
Jul 2018504127
Aug 2018623738
Sep 2018332716
Oct 2018305635
Nov 2018265636
Dec 2018134938
Total 2018527486331
Jan 2019163827
Feb 2019172727
Mar 2019314730
Apr 2019325827
May 2019255236
Jun 2019195719
Jul 2019165528
Aug 2019285029
Sep 2019216622
Oct 2019298423
Nov 2019276631
Dec 2019317039
Total 2019292670338
Jan 2020266326
Feb 2020255125
Mar 2020174723
Apr 202043622
May 202053917
Jun 2020194123
Jul 202072915
Aug 2020123836
Sep 2020135828
Oct 2020174926
Nov 2020194827
Dec 2020133625
Total 2020177535293
Jan 2021131714
Total 2021131714
Total1217332273484
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Chiral heliconical ground state of nanoscale pitch in a nematic liquid crystal of achiral molecular dimers
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Heliconical nematic liquid crystal
Dong Chen, Jan H. Porada, Justin B. Hooper, Arthur Klittnick, Yongqiang Shen, Michael R. Tuchband, Eva Korblova, Dmitry Bedrov, David M. Walba, Matthew A. Glaser, Joseph E. Maclennan, Noel A. Clark
Proceedings of the National Academy of Sciences Oct 2013, 110 (40) 15931-15936; DOI: 10.1073/pnas.1314654110

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Heliconical nematic liquid crystal
Dong Chen, Jan H. Porada, Justin B. Hooper, Arthur Klittnick, Yongqiang Shen, Michael R. Tuchband, Eva Korblova, Dmitry Bedrov, David M. Walba, Matthew A. Glaser, Joseph E. Maclennan, Noel A. Clark
Proceedings of the National Academy of Sciences Oct 2013, 110 (40) 15931-15936; DOI: 10.1073/pnas.1314654110
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Proceedings of the National Academy of Sciences: 110 (40)
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