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Research Article

Using chiral tactoids as optical probes to study the aggregation behavior of chromonics

Karthik Nayani, Jinxin Fu, Rui Chang, Jung Ok Park, and Mohan Srinivasarao
  1. aSchool of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332;
  2. bSchool of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA 30332;
  3. cSchool of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332;
  4. dCenter for Advanced Research in Optical Microscopy, Georgia Institute of Technology, Atlanta, GA 30332

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PNAS April 11, 2017 114 (15) 3826-3831; first published March 23, 2017; https://doi.org/10.1073/pnas.1614620114
Karthik Nayani
aSchool of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332;
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Jinxin Fu
aSchool of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332;
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Rui Chang
bSchool of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA 30332;
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Jung Ok Park
aSchool of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332;
cSchool of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332;
dCenter for Advanced Research in Optical Microscopy, Georgia Institute of Technology, Atlanta, GA 30332
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Mohan Srinivasarao
aSchool of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332;
cSchool of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332;
dCenter for Advanced Research in Optical Microscopy, Georgia Institute of Technology, Atlanta, GA 30332
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  • For correspondence: mohan@mse.gatech.edu
  1. Edited by David A. Weitz, Harvard University, Cambridge, MA, and approved February 21, 2017 (received for review September 1, 2016)

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Article Information

vol. 114 no. 15 3826-3831
DOI: 
https://doi.org/10.1073/pnas.1614620114
PubMed: 
28336530

Published By: 
National Academy of Sciences
Print ISSN: 
0027-8424
Online ISSN: 
1091-6490
History: 
  • Published in issue April 11, 2017.
  • Published first March 23, 2017.

Copyright & Usage: 
Freely available online through the PNAS open access option.

Author Information

  1. Karthik Nayania,1,
  2. Jinxin Fua,1,
  3. Rui Changb,
  4. Jung Ok Parka,c,d, and
  5. Mohan Srinivasaraoa,c,d,2
  1. aSchool of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332;
  2. bSchool of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA 30332;
  3. cSchool of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332;
  4. dCenter for Advanced Research in Optical Microscopy, Georgia Institute of Technology, Atlanta, GA 30332
  1. Edited by David A. Weitz, Harvard University, Cambridge, MA, and approved February 21, 2017 (received for review September 1, 2016)

Footnotes

  • ↵1K.N. and J.F. contributed equally to this work.

  • ↵2To whom correspondence should be addressed. Email: mohan{at}mse.gatech.edu.
  • Author contributions: K.N., J.O.P., and M.S. designed research; K.N., J.F., and R.C. performed research; K.N., J.F., and R.C. analyzed data; and K.N., J.F., R.C., J.O.P., and M.S. wrote the paper.

  • The authors declare no conflict of interest.

  • This article is a PNAS Direct Submission.

  • This article contains supporting information online at www.pnas.org/lookup/suppl/doi:10.1073/pnas.1614620114/-/DCSupplemental.

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Mar 20172104118216
Apr 20173438177469
May 201733524184
Jun 20172021198
Jul 20173312148
Aug 20171012423
Sep 20171201719
Oct 2017761527
Nov 2017551511
Dec 201755634
Total 201768174281129
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Feb 2018443818
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Apr 2018959218
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Total 2018753820190
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Jul 201922125
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Sep 201922311
Oct 201983224
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Total 201959328211
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Mar 2021135
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Total771919771740
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Unusual behavior of chiral chromonic tactoids
Karthik Nayani, Jinxin Fu, Rui Chang, Jung Ok Park, Mohan Srinivasarao
Proceedings of the National Academy of Sciences Apr 2017, 114 (15) 3826-3831; DOI: 10.1073/pnas.1614620114

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Unusual behavior of chiral chromonic tactoids
Karthik Nayani, Jinxin Fu, Rui Chang, Jung Ok Park, Mohan Srinivasarao
Proceedings of the National Academy of Sciences Apr 2017, 114 (15) 3826-3831; DOI: 10.1073/pnas.1614620114
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Proceedings of the National Academy of Sciences: 114 (15)
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  • Article
    • Abstract
    • Results and Discussion
    • Conclusions
    • Materials and Methods
    • SI Numerical Calculation of the Elastic Free Energy of Twisted-Bipolar Tactoids
    • SI Twist Angle Measurement of the Tactoids with the Unique Director Configuration
    • SI Quantifying the Shape of Bipolar and Twisted-Bipolar Tactoids
    • SI Raman Measurements
    • SI Influence of Confining Surfaces
    • SI Materials and Methods
    • Acknowledgments
    • Footnotes
    • References
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