Skip to main content
  • Submit
  • About
    • Editorial Board
    • PNAS Staff
    • FAQ
    • Accessibility Statement
    • Rights and Permissions
    • Site Map
  • Contact
  • Journal Club
  • Subscribe
    • Subscription Rates
    • Subscriptions FAQ
    • Open Access
    • Recommend PNAS to Your Librarian
  • Log in
  • My Cart

Main menu

  • Home
  • Articles
    • Current
    • Special Feature Articles - Most Recent
    • Special Features
    • Colloquia
    • Collected Articles
    • PNAS Classics
    • List of Issues
  • Front Matter
  • News
    • For the Press
    • This Week In PNAS
    • PNAS in the News
  • Podcasts
  • Authors
    • Information for Authors
    • Editorial and Journal Policies
    • Submission Procedures
    • Fees and Licenses
  • Submit
  • About
    • Editorial Board
    • PNAS Staff
    • FAQ
    • Accessibility Statement
    • Rights and Permissions
    • Site Map
  • Contact
  • Journal Club
  • Subscribe
    • Subscription Rates
    • Subscriptions FAQ
    • Open Access
    • Recommend PNAS to Your Librarian

User menu

  • Log in
  • My Cart

Search

  • Advanced search
Home
Home

Advanced Search

  • Home
  • Articles
    • Current
    • Special Feature Articles - Most Recent
    • Special Features
    • Colloquia
    • Collected Articles
    • PNAS Classics
    • List of Issues
  • Front Matter
  • News
    • For the Press
    • This Week In PNAS
    • PNAS in the News
  • Podcasts
  • Authors
    • Information for Authors
    • Editorial and Journal Policies
    • Submission Procedures
    • Fees and Licenses

New Research In

Physical Sciences

Featured Portals

  • Physics
  • Chemistry
  • Sustainability Science

Articles by Topic

  • Applied Mathematics
  • Applied Physical Sciences
  • Astronomy
  • Computer Sciences
  • Earth, Atmospheric, and Planetary Sciences
  • Engineering
  • Environmental Sciences
  • Mathematics
  • Statistics

Social Sciences

Featured Portals

  • Anthropology
  • Sustainability Science

Articles by Topic

  • Economic Sciences
  • Environmental Sciences
  • Political Sciences
  • Psychological and Cognitive Sciences
  • Social Sciences

Biological Sciences

Featured Portals

  • Sustainability Science

Articles by Topic

  • Agricultural Sciences
  • Anthropology
  • Applied Biological Sciences
  • Biochemistry
  • Biophysics and Computational Biology
  • Cell Biology
  • Developmental Biology
  • Ecology
  • Environmental Sciences
  • Evolution
  • Genetics
  • Immunology and Inflammation
  • Medical Sciences
  • Microbiology
  • Neuroscience
  • Pharmacology
  • Physiology
  • Plant Biology
  • Population Biology
  • Psychological and Cognitive Sciences
  • Sustainability Science
  • Systems Biology
Research Article

Recycled ancient ghost carbonate in the Pitcairn mantle plume

View ORCID ProfileXiao-Jun Wang, View ORCID ProfileLi-Hui Chen, Albrecht W. Hofmann, Takeshi Hanyu, Hiroshi Kawabata, Yuan Zhong, Lie-Wen Xie, Jin-Hua Shi, View ORCID ProfileTakashi Miyazaki, Yuka Hirahara, Toshiro Takahashi, Ryoko Senda, Qing Chang, Bogdan S. Vaglarov, and View ORCID ProfileJun-Ichi Kimura
PNAS August 28, 2018 115 (35) 8682-8687; first published August 13, 2018; https://doi.org/10.1073/pnas.1719570115
Xiao-Jun Wang
aState Key Laboratory for Mineral Deposits Research, School of Earth Sciences and Engineering, Nanjing University, 210023 Nanjing, China;
  • Find this author on Google Scholar
  • Find this author on PubMed
  • Search for this author on this site
  • ORCID record for Xiao-Jun Wang
Li-Hui Chen
aState Key Laboratory for Mineral Deposits Research, School of Earth Sciences and Engineering, Nanjing University, 210023 Nanjing, China;
  • Find this author on Google Scholar
  • Find this author on PubMed
  • Search for this author on this site
  • ORCID record for Li-Hui Chen
  • For correspondence: chenlh@nju.edu.cn albrecht.hofmann@mpic.de
Albrecht W. Hofmann
bAbteilung Klimageochemie, Max-Planck-Institut für Chemie, D-55128 Mainz, Germany;
  • Find this author on Google Scholar
  • Find this author on PubMed
  • Search for this author on this site
  • For correspondence: chenlh@nju.edu.cn albrecht.hofmann@mpic.de
Takeshi Hanyu
cDepartment of Solid Earth Geochemistry, Japan Agency for Marine-Earth Science and Technology, 237-0061 Yokosuka, Japan;
  • Find this author on Google Scholar
  • Find this author on PubMed
  • Search for this author on this site
Hiroshi Kawabata
dFaculty of Science and Technology, Kochi University, 780-8520 Kochi, Japan;
  • Find this author on Google Scholar
  • Find this author on PubMed
  • Search for this author on this site
Yuan Zhong
aState Key Laboratory for Mineral Deposits Research, School of Earth Sciences and Engineering, Nanjing University, 210023 Nanjing, China;
  • Find this author on Google Scholar
  • Find this author on PubMed
  • Search for this author on this site
Lie-Wen Xie
eState Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, 100029 Beijing, China
  • Find this author on Google Scholar
  • Find this author on PubMed
  • Search for this author on this site
Jin-Hua Shi
aState Key Laboratory for Mineral Deposits Research, School of Earth Sciences and Engineering, Nanjing University, 210023 Nanjing, China;
  • Find this author on Google Scholar
  • Find this author on PubMed
  • Search for this author on this site
Takashi Miyazaki
cDepartment of Solid Earth Geochemistry, Japan Agency for Marine-Earth Science and Technology, 237-0061 Yokosuka, Japan;
  • Find this author on Google Scholar
  • Find this author on PubMed
  • Search for this author on this site
  • ORCID record for Takashi Miyazaki
Yuka Hirahara
cDepartment of Solid Earth Geochemistry, Japan Agency for Marine-Earth Science and Technology, 237-0061 Yokosuka, Japan;
  • Find this author on Google Scholar
  • Find this author on PubMed
  • Search for this author on this site
Toshiro Takahashi
cDepartment of Solid Earth Geochemistry, Japan Agency for Marine-Earth Science and Technology, 237-0061 Yokosuka, Japan;
  • Find this author on Google Scholar
  • Find this author on PubMed
  • Search for this author on this site
Ryoko Senda
cDepartment of Solid Earth Geochemistry, Japan Agency for Marine-Earth Science and Technology, 237-0061 Yokosuka, Japan;
  • Find this author on Google Scholar
  • Find this author on PubMed
  • Search for this author on this site
Qing Chang
cDepartment of Solid Earth Geochemistry, Japan Agency for Marine-Earth Science and Technology, 237-0061 Yokosuka, Japan;
  • Find this author on Google Scholar
  • Find this author on PubMed
  • Search for this author on this site
Bogdan S. Vaglarov
cDepartment of Solid Earth Geochemistry, Japan Agency for Marine-Earth Science and Technology, 237-0061 Yokosuka, Japan;
  • Find this author on Google Scholar
  • Find this author on PubMed
  • Search for this author on this site
Jun-Ichi Kimura
cDepartment of Solid Earth Geochemistry, Japan Agency for Marine-Earth Science and Technology, 237-0061 Yokosuka, Japan;
  • Find this author on Google Scholar
  • Find this author on PubMed
  • Search for this author on this site
  • ORCID record for Jun-Ichi Kimura
  1. Edited by Richard W. Carlson, Carnegie Institution for Science, Washington, DC, and approved July 17, 2018 (received for review November 9, 2017)

  • Article
  • Figures & SI
  • Info & Metrics
  • PDF
Loading

Significance

Lavas from Pitcairn Island are the best candidates for exploring the origin of the enigmatic EM1 component found in some mantle plumes because they show the most extreme isotopic compositions of Sr, Nd, Hf, and Pb that define the EM1 component. We find that these lavas have the lowest δ26Mg values so far recorded in oceanic basalts. Subducted late Archean dolomite-bearing sediments are the most plausible source of the low-δ26Mg feature of Pitcairn lavas. This requires that an ancient, originally sedimentary component has been emplaced near the core–mantle boundary to ultimately become part of the Pitcairn plume source.

Abstract

The extreme Sr, Nd, Hf, and Pb isotopic compositions found in Pitcairn Island basalts have been labeled enriched mantle 1 (EM1), characterizing them as one of the isotopic mantle end members. The EM1 origin has been vigorously debated for over 25 years, with interpretations ranging from delaminated subcontinental lithosphere, to recycled lower continental crust, to recycled oceanic crust carrying ancient pelagic sediments, all of which may potentially generate the requisite radiogenic isotopic composition. Here we find that δ26Mg ratios in Pitcairn EM1 basalts are significantly lower than in normal mantle and are the lowest values so far recorded in oceanic basalts. A global survey of Mg isotopic compositions of potentially recycled components shows that marine carbonates constitute the most common and typical reservoir invariably characterized by extremely low δ26Mg values. We therefore infer that the subnormal δ26Mg of the Pitcairn EM1 component originates from subducted marine carbonates. This, combined with previously published evidence showing exceptionally unradiogenic Pb as well as sulfur isotopes affected by mass-independent fractionation, suggests that the Pitcairn EM1 component is most likely derived from late Archean subducted carbonate-bearing sediments. However, the low Ca/Al ratios of Pitcairn lavas are inconsistent with experimental evidence showing high Ca/Al ratios in melts derived from carbonate-bearing mantle sources. We suggest that carbonate–silicate reactions in the late Archean subducted sediments exhausted the carbonates, but the isotopically light magnesium of the carbonate was incorporated in the silicates, which then entered the lower mantle and ultimately became the Pitcairn plume source.

  • Pitcairn mantle plume
  • EM1
  • magnesium isotopes
  • ancient carbonate-bearing sediments

The geochemical and isotopic diversity of ocean island basalts (OIBs) erupted at hot spots is generated by partial melting of heterogeneous mantle sources that contain recycled crustal and/or lithospheric mantle materials (1, 2). Specific recycled components generally show radiogenic isotope ratios distinct from the ambient mantle, and radiogenic isotopes are therefore widely used tools for tracing them. However, this tool can be compromised by the fact that similar radiogenic isotope features can appear in different geological reservoirs. Thus, the exceptionally unradiogenic Pb isotopes observed in intraplate enriched mantle 1 [EM1 (3)] lavas have been variously attributed to recycled ancient pelagic sediments (4⇓⇓–7), subducted oceanic plateau (8), recycled lower continental crust (LCC) (9), delaminated subcontinental lithospheric mantle (10), and recycled mafic sediments (11). Fortunately, a combination of stable and radiogenic isotopes can sometimes be used to discriminate the nature of recycled materials less ambiguously. Recently, Delavault et al. (7) demonstrated the presence of sulfur isotopes affected by mass-independent fractionation in sulfides contained by Pitcairn lavas, which are likely to have been introduced into the Pitcairn source by subduction of ancient sediments. Here we use a stable isotope tracer, magnesium, which undergoes strong isotopic fractionation during precipitation of carbonate from seawater/pore fluids (12), producing distinctively low δ26Mg values in marine carbonates. Because of this, it appears to be an excellent tracer of a more specific recycled component than, for example, oxygen isotopes.

There are many models for the creation of chemical heterogeneity in the source regions of OIBs that invoke the recycling of oceanic crust and lithologically different sediments through the mantle (5, 13⇓–15). The existing Mg isotope data show that marine sediments and altered oceanic crust have variable Mg isotopic signatures that differ significantly from those of normal peridotitic mantle (Fig. 1). In particular, marine carbonates stand out by their extremely light Mg isotopes, reaching values of δ26Mg as low as −5‰. This provides the opportunity to use anomalous Mg isotopic signatures in erupted OIBs as tracers of their sources. A recent Mg isotopic study on Hawaii and Louisville basalts presented a first test of this proposition, showing small but significant differences in δ26Mg (16). However, the current Mg isotope database for OIBs is still very small, and the Mg isotope characteristics of the several classical mantle species, i.e., HIMU (high μ = 238U/204Pb), EM1, and enriched mantle 2 (3), remain to be evaluated. Here we focus on the EM1 end member by presenting whole-rock Mg isotopic analyses of Rarotonga and Pitcairn Island lavas. The combination of Mg isotopes with Sr–Nd–Hf–Pb isotopes provides critical evidence for the return of ancient, subducted dolomite-derived magnesium in EM1 lavas erupted at Earth’s surface.

Fig. 1.
  • Download figure
  • Open in new tab
  • Download powerpoint
Fig. 1.

Mg isotopic compositions of mantle rocks and some potentially recycled components. The average δ26Mg value, the SD (1 SD), and the number of samples (N) are given for each reservoir. For peridotite xenoliths and abyssal peridotites, the error bars are covered by the symbols for the average values. The vertical gray bar represents the δ26Mg range of peridotitic mantle [−0.23 ± 0.04‰ (20)]. See SI Appendix, Part 3 for data sources.

Pitcairn mantle plume has recently been identified as a category 1–primary plume, by French and Romanowicz (17), who used waveform seismic tomography to trace it down to the core–mantle boundary. Identifying the nature and age of surface-derived geochemical signatures in such a plume therefore provides important constraints on the nature and time scale of deep mantle circulation processes.

Results

We analyzed 12 samples from Pitcairn Island (SI Appendix, Fig. S1). Seven of the samples come from the shield-building Tedside volcanics, and five others are from the late-stage, posterosional volcanics including Pulawana, Christians Cave Formation, and Adamstown volcanics. Duncan et al. (18) reported K-Ar ages for Tedside and late-stage volcanics of 0.95–0.76 and 0.67–0.45 Ma, respectively. The whole-rock Mg isotopic compositions, and newly measured major and trace elements, as well as the Sr–Nd–Hf–Pb isotope ratios are reported in Datasets S1–S3. For comparison, we also analyzed Mg isotopes of four well-characterized samples (19) from Rarotonga Island (SI Appendix, Fig. S1), which show Sr–Nd–Hf–Pb isotope ratios trending toward the EM1 end member (5, 19). All of our samples belong to the alkaline series, and most of them are relatively unevolved rocks with SiO2 < 52 wt % (SI Appendix, Fig. S2). The Tedside basalts have robust EM1 end member isotopic signatures compared with the late-stage Pitcairn lavas and Rarotonga basalts (SI Appendix, Fig. S3).

The δ26Mg values of Tedside basalts range from −0.40 to −0.31‰, clearly lower than those of the late-stage Pitcairn lavas (−0.30 to −0.16‰), peridotitic mantle [δ26Mg = −0.23 ± 0.04‰ (20) or δ26Mg = −0.25 ± 0.04‰ (21)], and other typical OIBs (Hawaii, Louisville, and Rarotonga) (Fig. 2). The lower end of the Pitcairn range is the lowest value observed so far in OIBs (see the compilation in ref. 21) and is close to the upper bound of the continental intraplate EM1 end member basalts from Wudalianchi and Erkeshan [hereafter referred to as “intracontinental EM1 basalts”; δ26Mg = −0.57 to −0.45‰ (22, 23)] in northeast China (Fig. 3). The δ26Mg values of Pitcairn and Rarotonga EM1 basalts, taken together, exhibit significant negative correlations with 87Sr/86Sr and positive correlations with 206Pb/204Pb, εNd, and εHf (Fig. 3). Inclusion of the intracontinental EM1 basalts strengthens these correlations and further extends their range to even lower δ26Mg values. A common heritage of oceanic and continental EM1 magmas is further substantiated by the correlation between δ26Mg and CaO/Al2O3 (Fig. 4). Oceanic EM1 lavas exhibit the lowest CaO/Al2O3 ratios within the global OIB association (24), and the intracontinental EM1 basalts have even lower CaO/Al2O3 ratios. Therefore, we consider all these EM1-type intraplate lavas as a group to explore the origin of the characteristic EM1 component.

Fig. 2.
  • Download figure
  • Open in new tab
  • Download powerpoint
Fig. 2.

δ26Mg versus MgO for the Pitcairn Island and Rarotonga samples. Also shown are published data (16, 59) for other OIBs. The subnormal δ26Mg character of the Tedside lavas from Pitcairn is clear. Error bars on δ26Mg represent 2 SD uncertainties.

Fig. 3.
  • Download figure
  • Open in new tab
  • Download powerpoint
Fig. 3.

δ26Mg versus (A) 87Sr/86Sr, (B) 206Pb/204Pb, (C) εNd, and (D) εHf isotopic arrays for mixing of ambient peridotite and recycled material. Recycled material is the mix of recycled oceanic crust (R) and residual sediment component (S) in various mixing proportions. For details of how the composition of the residual sediment component (S) is derived, see Discussion and SI Appendix, Part 2. Mixing curves are marked in 10% increments. An enlarged figure (SI Appendix, Fig. S6) showing mixtures of all of the three end members is given in SI Appendix. The modeling parameters can be found in SI Appendix, Table S1. Also plotted are data for intracontinental EM1 basalts (see SI Appendix, Part 3 for data sources). A separate mixing curve for these lavas is required in B because the estimated age and μ (238U/204Pb) value (22) of the subducted sediments that evolved into the EM1 component in their source are different from those of the Pitcairn EM1 component (7). For average MORB, the δ26Mg value (−0.25 ± 0.06‰, 2 SD) is from ref. 59, and radiogenic isotope ratios are the mean (±95% confidence interval on the mean) given in ref. 33. Others are as in Fig. 2.

Fig. 4.
  • Download figure
  • Open in new tab
  • Download powerpoint
Fig. 4.

Extreme EM1 lavas show exceptionally low CaO/Al2O3 and δ26Mg values. The late-stage Pitcairn lavas are omitted here because their CaO/Al2O3 ratios have been severely modified by fractionation of clinopyroxene and plagioclase. Also plotted are literature data for other types of basalts (see SI Appendix, Part 3 for data sources). Shaded regions labeled I (gray) and II (green) denote the CaO/Al2O3 ranges for experimental partial melts of pyroxenite (55, 56) and carbonated eclogite (44). For Pitcairn primary magmas, the CaO/Al2O3 ratio is from ref. 24; for average MORB, it is the calculated mean (±95% confidence interval on the mean) based on the data in ref. 33. Others are as in Fig. 3.

Discussion

Subnormal δ26Mg of the EM1 Mantle Sources.

The analyzed OIB samples are fresh, and no secondary carbonates can be observed (SI Appendix, Fig. S4). Their loss on ignition (LOI) values are very low (mostly <1.0 wt %; Dataset S2), and there is no correlation between δ26Mg and LOI, precluding any obvious chemical weathering. Seawater has lower δ26Mg [−0.83‰ (21)] value than reported values of OIBs (16, 21); thus, seawater contamination might potentially modify the Mg isotopic composition of OIBs. However, seawater has much lower Mg concentrations [0.128 wt % (25)] than our basalt samples with low δ26Mg values, and more than 90% of seawater would have to be added to the basalt to shift the δ26Mg of basalt from −0.25 to −0.40‰. This can be ruled out because of the low LOI of our samples. Hence, the low δ26Mg values of Tedside basalts are unlikely to be the result of postmagmatic alteration.

Fractionation of olivine, pyroxene, and plagioclase dominate the major element variations of Pitcairn lavas with MgO >4 wt %, and fractionation of Fe-Ti–rich phases (e.g., ilmenite) is apparent in lavas with MgO <4 wt % (SI Appendix, Fig. S2). Fractionation of the former group of phases can induce very minor [<0.07‰ (26)] Mg isotope fractionation, but that of the latter may lead to considerable fractionation (27). Therefore, because Mg isotopic variation in the two highly evolved samples (MgO < 3 wt %; Fig. 2) might be largely controlled by fractionation of Fe-Ti–oxides, we ignore these samples hereafter. Overall, crystal fractionation cannot be responsible for lowering δ26Mg values, because the lowest δ26Mg (−0.40‰) values appear in high-MgO (>8 wt %) Tedside samples, and these should reflect the inherent properties of the primary magmas. For Rarotonga lavas, their high MgO contents (Fig. 2 and SI Appendix, Fig. S2) indicate that their normal mantle-like δ26Mg values are those of the respective primary melts. Isotope fractionation during partial melting also cannot produce the low-δ26Mg feature of Tedside samples, because the largest δ26Mg difference between partial melts and solid residue is less than 0.1‰, no matter whether the initial source is a garnet pyroxenite or a peridotite (16). In summary, neither crystallization nor partial melting effects can explain the observed low δ26Mg values (as low as −0.40‰) in EM1-type OIBs, and the subnormal δ26Mg lavas require an isotopically light mantle source component, as was also the case for the intracontinental EM1 basalts (22). Given the correlations between δ26Mg and Sr–Nd–Hf–Pb isotopes of EM1 lavas (Fig. 3), we conclude that the unradiogenic isotope ratios of Pb, Nd, and Hf, together with the elevated 87Sr/86Sr ratios, are all coupled with subnormal δ26Mg values in the EM1 component.

The Origin of EM1.

The low δ26Mg values of Pitcairn lavas are clearly at odds with some of the earlier models advocating delaminated subcontinental lithosphere or recycled LCC, given that neither of these reservoirs have primary subnormal δ26Mg (21, 22). A summary of Mg isotope data for 160 global peridotite xenoliths that sample the subcontinental lithospheric mantle with various parageneses, chemical compositions, and ages definitely shows no evidence for subnormal δ26Mg values that would qualify them as the EM1 source component (Fig. 1). Although some peridotite xenoliths have been extensively metasomatised by carbonatite or CO2-rich silicate melts, they still maintain mantle-like δ26Mg values [−0.27 to −0.16‰ (28)]. The δ26Mg values of cratonic eclogites are highly heterogeneous and can be as low as −1.0‰ (29), and such rocks may thus potentially constitute a low-δ26Mg origin. However, such eclogites are only a minor (<1 vol %) component of subcontinental lithospheric mantle (30). They are usually thought to represent the composition of recycled ancient oceanic crust (29, 31, 32). The reconstructed bulk compositions of these eclogites, as represented by the 2.9-Ga Lace basaltic eclogites, yield median Sm/Nd and Lu/Hf ratios of 0.40 and 0.27, respectively (32). These are higher than the average values of midocean ridge basalts (MORB) [Sm/Nd = 0.326 and Lu/Hf = 0.195 (33)]. Therefore, the long-term isotopic evolution of the cratonic eclogites in the mantle should lead to highly radiogenic Nd–Hf isotopic compositions (32) rather than the observed, unradiogenic EM1-type end member. A collection of LCC xenoliths that have not been affected by carbonate metasomatism indicates that normal LCC also has mantle-like δ26Mg value [δ26Mg = −0.26 ± 0.06‰ (34)], although a few of the intensively metasomatised low-MgO samples do have δ26Mg values as low as −0.7‰ (34). Therefore, on balance, models invoking delaminated subcontinental lithosphere and/or LCC are difficult to reconcile with the consistently subnormal δ26Mg of the EM1 sources.

Recycled ancient ocean plateau material, which contains cumulus gabbro, has also been suggested to be the origin of Pitcairn EM1 source (8). This possibility is inconsistent with the low-δ26Mg feature of the Pitcairn EM1 source because Mg isotopic compositions of gabbros from both oceanic crust and ophiolite do not deviate from that of peridotitic mantle (35, 36). Similarly, recycled mafic sediments consist of olivine and pyroxene, and their weathering products (i.e., clay) (11) are not expected to satisfy the subnormal δ26Mg signature of the Pitcairn EM1 component, because these minerals show mantle-like or even higher δ26Mg values (21).

Recycled ancient pelagic sediments have repeatedly been invoked as EM1 mantle sources (4⇓⇓–7). This interpretation is supported here by the systematically lowered Nb/Th ratios and the positive correlations in the plots of εNd and 206Pb/204Pb versus Nb/Th for Pitcairn Island basalts (SI Appendix, Fig. S5), which require some continental crust–derived, most likely sedimentary sources. In particular, the recent discovery of mass-independent fractionation of sulfur isotopes (S-MIF down to Δ33S = −0.8‰) in sulfides contained by Pitcairn lavas, along with three-stage Pb isotope growth modeling, has constrained the late Archean age (2.5–2.6 Ga) of the recycled sediments incorporated into the Pitcairn EM1 source (7). Our results are fully consistent with this interpretation, but they add an additional constraint that further specifies the nature of the recycled sediments. Thus, the recycled sediments must initially contain significant amounts of carbonates, to satisfy the low-δ26Mg feature of Pitcairn EM1 component. Among potentially subducted materials, marine carbonates identify the low-δ26Mg end member by their extremely light Mg isotopic compositions, which are remarkably distinct from other Mg reservoirs and peridotitic mantle (Fig. 1). Accordingly, marine carbonates with extremely low δ26Mg values, especially for the Mg-rich carbonates (dolomite), appear to be the unique reservoir capable of dominating the Mg isotopic compositions of bulk sediments. Because the metamorphic equivalents of the subducted sediments tend to preserve their original Mg isotopic compositions (37), recycled Archean dolomite-bearing sediments provide a likely origin of the low-δ26Mg feature of EM1 component. In the following sections, we discuss additional aspects of this proposition.

Archean Carbonate Deposits.

How common are marine carbonate deposits in Archean time? Veizer et al. (38) reviewed the geochemistry of Archean carbonates with geological attributes of marine sediments and noted that they are “a minor component of the Archean greenstone belts.” Nevertheless, they do occur in many such greenstone belts, including the Yellowknife Supergroup; the Abitibi, Michipicoten, Uchi, and Wabigoon Greenstone Belts in Canada; the Main Greenstone Belt of Zimbabwe; the Sargur Marbles of India; the Warrawoona Group of Australia (38, 39); and the Neoarchean Transvaal carbonate platform, South Africa (40). Most of these deposits appear to have been originally formed as aragonitic limestones, but many have been replaced by dolomite and/or ankerite during sedimentation and diagenesis (38, 41), thus constituting a significant Mg reservoir with isotopically light magnesium. We conclude that although such carbonates may indeed be minor constituents of Archean sedimentary sequences, they are by no means uncommon. In this context, it is important to remember that extreme EM1 end member basalts are also rare in the oceanic basalt family.

Ghost Carbonate in the Pitcairn Source.

Another question is, how was the isotopically light Mg of dolomite in originally subducted sediments introduced into the EM1 source? One possible way is that the bulk subducted dolomite, together with its surrounding silicate sediments, was directly incorporated into the Pitcairn EM1 source. However, this can be largely ruled out by the major element compositions of Pitcairn EM1 lavas. These lavas are characterized by the lowest CaO and CaO/Al2O3 ratios but among the highest SiO2 contents in the global OIB database (24, 42, 43). Their low CaO/Al2O3 ratios (0.5–0.6) are not induced by extensive fractionation of clinopyroxene and plagioclase, and the estimated CaO/Al2O3 ratio of their primary melts is as low as 0.54 (24). By contrast, experimental work has shown that partial melting of carbonate-bearing mantle rocks (peridotite/pyroxenite) produces melts with high CaO and low SiO2 contents (44, 45). Notably, the HIMU-like low-δ26Mg basalts from New Zealand, which were suggested to derive from a carbonated eclogite source (28), show extremely high CaO/Al2O3 and low SiO2 (Fig. 4 and ref. 46), features that are distinct from the low-δ26Mg EM1 basalts. Accordingly, the low CaO and CaO/Al2O3 of Pitcairn lavas are inconsistent with the presence of carbonate in the direct mantle source. An alternative possibility is that the isotopically light Mg remains in the EM1 source as a “ghost” of the originally subducted dolomite, but the carbonate component of the dolomite has been lost. This is somewhat analogous to the interpretations of Hawaii and Mangaia hot spot lavas, where it has been shown that the original chemical or isotopic identity of recycled crustal materials may be present only as a ghost or phantom signature in the mantle source, whereas their actual lithological identity has been completely lost (47, 48). In the present case, a prerequisite is that the isotopically light Mg of dolomite in the originally subducted sediments must be inherited by Mg-silicate and then be incorporated into the EM1 source. Below, we discuss possible mechanisms for such processes.

Possible Decarbonation Mechanisms.

As suggested above, the low-δ26Mg feature of Pitcairn EM1 component is inferred to be derived from dolomite in Archean subducted sediments. Because the Archean subduction zones are hot, such sediments are prone to losing their carbon inventory during subduction, through carbonate melting or subsolidus decarbonation (49). According to experimentally determined solidi (50), carbonate-bearing sediments may possibly melt within the pressure range of 6–9 GPa in hot subduction zones. Because the carbonatite melts produced by melting of carbonate-bearing sediments in the pressure range of 6–9 GPa are Ca-rich and Mg-poor (50), most of the dolomite-derived Mg budget will remain in the silicate residue after melt extraction. Therefore, the original low-δ26Mg signature is expected to be transferred to the silicate residue, thus providing one possible solution to the ghost carbonate Mg isotopic signature of the Pitcairn EM1 source. However, the extraction of carbonatite melts from subducted dolomite-bearing sediments would also remove large proportions of incompatible trace elements, and this should deplete the residual source in incompatible trace elements to such an extent that it would no longer be capable of generating highly trace element-enriched (Pitcairn-type) basalts. Therefore, carbonate melting is not a suitable decarbonizing mechanism to generate the particular EM1 source of Pitcairn lavas.

Another plausible mechanism is decarbonation reaction during subduction. The dolomite-bearing sediments are SiO2-rich, and they will be transformed into assemblages mainly consisting of dolomite + quartz/coesite at intermediate depths [<∼150 km (50)] or magnesite + coesite at greater depths [>∼150 km (50)]. During subduction of these assemblages, the following decarbonation reactions will easily occur under suitable P–T–fO2 conditions (51⇓–53):CaMg(CO3)2 (dolomite)+2SiO2 (coesite)→CaMgSi2O6 (diopside)+2CO2[1]CaMg(CO3)2 (dolomite)+2SiO2 (coesite)→CaMgSi2O6 (diopside)+2C(graphite/diamond)+2O2[2]MgCO3 (magnesite)+SiO2 (coesite)→ MgSiO3 (enstatite)+CO2.[3]Through these reactions, the silicate products (diopside and enstatite) can accommodate the Mg released by carbonate reactants, providing a feasible mechanism whereby the light Mg isotopic compositions of the original dolomite can be inherited by silicate products to form an isotopically light silicate component (21). Meanwhile, incompatible elements, including rare earth elements, can also be hosted in the silicate products, e.g., diopside. This silicate residue, bearing a ghost carbonate Mg isotopic signature inherited from the subducted carbonate, will ultimately become the plume source for the Pitcairn EM1 magmas.

Quantitative Evaluation of the Subducted Carbonate.

A three-component mixture of ancient sediment, old recycled oceanic crust, and ambient mantle peridotite has been suggested to constitute the Pitcairn mantle source by several previous studies proposing sediment recycling (4⇓⇓–7). Based on the Mg isotopic constraint in this study, we suggest that the ancient sediment component is the silicate residue of Archean (∼2.5 Ga) subducted dolomite-bearing sediments after dolomite was completely decarbonated during subduction (hereafter referred to as “residual sediment component”). Here the proportion of dolomite (δ26Mg = −2.68‰; SI Appendix, Table S1) in originally subducted sediments is assumed to be as high as 50%, so as to provide sufficient isotopically light Mg to affect the Pitcairn source. Thus, the residual sediment component has evolved from a late Archean (∼2.5 Ga) mixture initially consisting of 50% of dolomite and 50% of silicate sediments. To constrain the amount of originally subducted dolomite, we quantitatively modeled the mixing of ambient peridotite, recycled oceanic crust, and residual sediment component (Fig. 3 and SI Appendix, Fig. S6; see SI Appendix, Part 2 for details). However, we find that the unmodified mixture of dolomite and clastic sediment would not generate present-day isotopic compositions (SI Appendix, Table S1) consistent with the Pitcairn isotopic data (e.g., 87Sr/86Sr). We assume that this inconsistency is the result of trace element mobilization during subduction, and we therefore modified the trace element concentrations and parent/daughter isotopic ratios of the original mixture to obtain an appropriate residual sediment component whose isotopic compositions fit the mixing arrays in Fig. 3 and SI Appendix, Fig. S6. The final geochemical composition of the residual sediment component at ∼2.5 Ga (SI Appendix, Table S1) was determined by mixing the chemical and isotopic compositions of ∼2.5-Ga dolomites and ∼2.5-Ga silicate sediments and then removing a fraction of the total trace element budget (see SI Appendix, Part 2 for the detailed proportions of the removed part). After long-term (∼2.5 Gyr) isolated isotopic evolution, this sediment component can generate the extreme Pitcairn EM1 component. Considering the high uncertainty of the element fractions mobilized during dehydration/melting of subducting slabs (54), we argue that the modification of the trace element concentrations of the above mixture and the mixing modeling is reasonable. According to the modeling results (Fig. 3), the proportion of recycled materials (oceanic crust + sediment) in the Pitcairn source is about 3–36%, and the corresponding percentage of the residual sediment component varies from ∼1.5 to 18%. This means that the maximum amount of originally subducted dolomite (δ26Mg = −2.68‰) required to generate the low δ26Mg value of the Pitcairn source is ∼9%.

A new question arises whether the addition of CaO, inherited from the decomposed carbonate, to the Pitcairn source might increase the CaO/Al2O3 ratio of the Pitcairn lavas. A striking feature of the Pitcairn EM1 basalts is their exceptionally low CaO/Al2O3 ratios (Fig. 4). These are lower than the respective ratios found in MORB, in other types of OIBs, and in intracontinental HIMU-like basalts, and thus, they point to a pyroxenitic rather than peridotitic or carbonated eclogitic source lithology (Fig. 4; see also refs. 24, 55, and 56). Thus, we can answer the above question by estimating the effect of adding CaO released by ∼9% of originally subducted dolomite to a pyroxenite on the final melt composition produced by melting of this mix. In the absence of specific experiments addressing this question, we have approached the problem using pMELTS (57) (for detail, see SI Appendix, Fig. S7). The major element compositions of the mixed lithology were calculated by mixing of 91% of the chemical compositions of the MIX1G pyroxenite (55) and 9% of the chemical composition of dolomite (MgO = 21.86 wt % and CaO = 30.41 wt %; excluding CO2) and then normalized to 100%. The assumed melting pressure is 3 GPa. We plot the estimated residual modal abundances and CaO and CaO/Al2O3 values of the melts produced by 0–40% melting of the mixed lithology and the MIX1G pyroxenite in SI Appendix, Fig. S7. Results show that the addition of CaO to a pyroxenitic source increases the modal proportion of clinopyroxene at the expense of garnet (SI Appendix, Fig. S7A), but this has little effect on the CaO content and CaO/Al2O3 ratio of partial melts formed from this assemblage (SI Appendix, Fig. S7 B and C).

Comparison Between Oceanic and Subcontinental EM1 Sources.

The common element characterizing Pitcairn basalts and the intracontinental EM1 basalts is the involvement of an ancient, low-δ26Mg EM1 component in their mantle sources. The difference between the two settings may lie in the mechanism and location of the decarbonation processes required to account for the low CaO/Al2O3 ratios characterizing all EM1 basalts. For Pitcairn basalts, decarbonation proceeded most likely through carbonate–silicate reactions during subduction of dolomite-bearing sediments, as explained above. Intracontinental EM1 sources, on the other hand, were more likely decarbonated in the transition zone through the loss of carbonatite melts in the presence of K-hollandite (22), to account for their exceptionally high K/U and Ba/Th ratios, as well as their positive Zr–Hf anomalies, features that distinguish the intracontinental EM1 basalts from Pitcairn basalts (SI Appendix, Fig. S8). In any case, in both settings the magnesium isotopes are the main carbonate memory left in the EM1 source, and neither scenario supports actual subduction of substantial amounts of carbonates into the lower mantle, at least not during late Archean or early Proterozoic time when the subduction zones were presumably hotter than in geologically more recent times (49).

Materials and Methods

Major Oxides, Trace Elements, and Radiogenic Isotopes.

All rock samples were powdered in an alumina mill. Whole-rock geochemical compositions other than Mg isotopes were determined at the Japan Agency for Marine-Earth Science and Technology. Major and trace element compositions of whole-rock samples were analyzed by X-ray fluorescence spectrometry and inductively coupled plasma-quadrupole mass spectrometry (ICP-QMS). Pb, Sr, Nd, and Hf isotope ratios were measured on rock powders, after acid leaching, by thermal ionization mass spectrometry for Sr and Nd isotopes and multiple-collector ICP-MS for Pb and Hf isotopes. The detailed descriptions for sample preparation, chemical treatment, and analytical conditions are given in SI Appendix, Part 1.

Mg Isotopes.

Mg isotope analyses were performed at the Institute of Geology and Geophysics, Chinese Academy of Sciences, following previously well-established procedures (58). All samples and US Geological Survey (USGS) rock reference materials were weighed in Savillex screw-top beakers and then digested by using concentrated acids in the following sequence: (i) HF-HNO3 (3:2, vol/vol), (ii) HCl-HNO3 (3:1, vol/vol), and (iii) HNO3, until they were completely dissolved. The clear solutions were dried and dissolved in 2 mol/L HNO3 to obtain Mg concentrations of 20 ppm. Mg purification was achieved by cation exchange chromatography in Savillex microcolumns loaded with 2 mL of Bio-Rad AG50W-X12 (38–74 μm) resin. Each sample solution containing 20 μg Mg was loaded onto the resin. The same column procedure was carried out twice to obtain pure Mg solutions. One or two synthetic Mg solutions (IGGMg1-A) and at least two USGS rock reference materials were processed through the same column procedure with our investigated samples for checking the column chemistry. Purified sample and standard solutions were diluted to 2 ppm Mg using the same batch of 2% HNO3. After column chemistry, the Mg yields were ≥99.8% for all reference materials and unknown samples. The total procedural Mg blank during this study was less than 6 ng.

Mg isotopic compositions were measured by the sample–standard bracketing method on a Thermo Scientific Neptune MC-ICP-MS. A quartz dual cyclonic spray chamber combined with an Elemental Scientific Inc. 50 μL min−1 PFA MicroFlow Teflon nebulizer was used as the introduction system. Each sample was measured at least four times and then averaged. Mg isotopic compositions are expressed in δ notation as per mil (‰) deviation from DSM3: δXMg = [(XMg/24Mg)sample/(XMg/24Mg)DSM3 − 1] × 1,000, where X = 25 or 26. The long-term external precision was determined by repeated analyses of the international standards (DSM3 and Cambridge 1), in-house Mg standards (IGG Mg1 and SRM980), and various rock reference materials, and this value is better than ±0.06‰ (2 SD) for δ26Mg. Repeated measurements of the Cambridge 1 and IGG Mg1 at different dates yielded average δ26Mg values of −2.62 ± 0.05‰ (2 SD, n = 26) and −1.75 ± 0.05‰ (2 SD, n = 34), respectively. Comparison between our results of standards/USGS rock reference materials and published values is summarized in Dataset S4. In a plot of δ25Mgʹ vs. δ26Mgʹ (SI Appendix, Fig. S9), all samples fall along the mass-dependent fractionation line for Mg isotopes.

The data supporting the findings of this study are available in either the SI Appendix or the published works cited.

Acknowledgments

We thank J.-H. Yang, Y.-H. Yang, and C. Huang for their laboratory or technical support. We appreciate the highly constructive reviews from Matthew Jackson, Catherine Chauvel, and Paterno Castillo. This study was financially supported by the National Natural Science Foundation of China (Grants 41372064, 41688103, and 41672049), the Programme of Introducing Talents of Discipline to Universities of China (Grant B13021), and the Program A for Outstanding PhD Candidate of Nanjing University (Award 201701A005).

Footnotes

  • ↵1To whom correspondence may be addressed. Email: chenlh{at}nju.edu.cn or albrecht.hofmann{at}mpic.de.
  • ↵2Present address: Chiba Institute of Technology, 275-0016 Narashino, Japan.

  • ↵3Present address: Department of Geology, Niigata University, 950-2181 Niigata, Japan.

  • ↵4Present address: Faculty of Social and Cultural Studies, Kyushu University, 819-0395 Fukuoka, Japan.

  • Author contributions: X.-J.W. and L.-H.C. designed research; X.-J.W., L.-H.C., A.W.H., T.H., H.K., Y.Z., L.-W.X., J.-H.S., T.M., Y.H., T.T., R.S., Q.C., B.S.V., and J.-I.K. performed research; X.-J.W., L.-H.C., A.W.H., T.H., and H.K. analyzed data; and X.-J.W., L.-H.C., A.W.H., and T.H. wrote the paper.

  • The authors declare no conflict of interest.

  • This article is a PNAS Direct Submission.

  • This article contains supporting information online at www.pnas.org/lookup/suppl/doi:10.1073/pnas.1719570115/-/DCSupplemental.

Published under the PNAS license.

View Abstract

References

  1. ↵
    1. Hofmann AW
    (1997) Mantle geochemistry: The message from oceanic volcanism. Nature 385:219–229.
    OpenUrlCrossRef
  2. ↵
    1. White WM
    (2015) Probing the earth’s deep interior through geochemistry. Geochem Perspect 4:95–251.
    OpenUrl
  3. ↵
    1. Zindler A,
    2. Hart S
    (1986) Chemical geodynamics. Annu Rev Earth Planet Sci 14:493–571.
    OpenUrlCrossRef
  4. ↵
    1. Woodhead JD,
    2. McCulloch MT
    (1989) Ancient seafloor signals in Pitcairn Island lavas and evidence for large amplitude, small length-scale mantle heterogeneities. Earth Planet Sci Lett 94:257–273.
    OpenUrl
  5. ↵
    1. Chauvel C,
    2. Hofmann AW,
    3. Vidal P
    (1992) HIMU-EM: The French Polynesian connection. Earth Planet Sci Lett 110:99–119.
    OpenUrl
  6. ↵
    1. Eisele J, et al.
    (2002) The role of sediment recycling in EM-1 inferred from Os, Pb, Hf, Nd, Sr isotope and trace element systematics of the Pitcairn hotspot. Earth Planet Sci Lett 196:197–212.
    OpenUrl
  7. ↵
    1. Delavault H,
    2. Chauvel C,
    3. Thomassot E,
    4. Devey CW,
    5. Dazas B
    (2016) Sulfur and lead isotopic evidence of relic Archean sediments in the Pitcairn mantle plume. Proc Natl Acad Sci USA 113:12952–12956.
    OpenUrlAbstract/FREE Full Text
  8. ↵
    1. Gasperini D, et al.
    (2000) Evidence from Sardinian basalt geochemistry for recycling of plume heads into the Earth’s mantle. Nature 408:701–704.
    OpenUrlCrossRefPubMed
  9. ↵
    1. Willbold M,
    2. Stracke A
    (2010) Formation of enriched mantle components by recycling of upper and lower continental crust. Chem Geol 276:188–197.
    OpenUrlCrossRef
  10. ↵
    1. McKenzie D,
    2. O’Nions RK
    (1983) Mantle reservoirs and ocean island basalts. Nature 301:229–231.
    OpenUrlCrossRef
  11. ↵
    1. Castillo PR
    (2017) An alternative explanation for the Hf-Nd mantle array. Sci Bull (Beijing) 62:974–975.
    OpenUrl
  12. ↵
    1. Wombacher F, et al.
    (2011) Magnesium stable isotope fractionation in marine biogenic calcite and aragonite. Geochim Cosmochim Acta 75:5797–5818.
    OpenUrlCrossRef
  13. ↵
    1. Hofmann AW,
    2. White WM
    (1982) Mantle plumes from ancient oceanic crust. Earth Planet Sci Lett 57:421–436.
    OpenUrl
  14. ↵
    1. Jackson MG, et al.
    (2007) The return of subducted continental crust in Samoan lavas. Nature 448:684–687.
    OpenUrlCrossRefPubMed
  15. ↵
    1. White WM,
    2. Hofmann AW
    (1982) Sr and Nd isotope geochemistry of oceanic basalts and mantle evolution. Nature 296:821–825.
    OpenUrlCrossRef
  16. ↵
    1. Zhong Y, et al.
    (2017) Magnesium isotopic variation of oceanic island basalts generated by partial melting and crustal recycling. Earth Planet Sci Lett 463:127–135.
    OpenUrl
  17. ↵
    1. French SW,
    2. Romanowicz B
    (2015) Broad plumes rooted at the base of the Earth’s mantle beneath major hotspots. Nature 525:95–99.
    OpenUrlCrossRefPubMed
  18. ↵
    1. Duncan RA,
    2. McDougall I,
    3. Carter RM,
    4. Coombs DS
    (1974) Pitcairn Island-another Pacific hot spot? Nature 251:679–682.
    OpenUrlCrossRef
  19. ↵
    1. Hanyu T, et al.
    (2011) Geochemical characteristics and origin of the HIMU reservoir: A possible mantle plume source in the lower mantle. Geochem Geophys Geosyst 12:Q0AC09.
    OpenUrl
  20. ↵
    1. Lai YJ, et al.
    (2015) The influence of melt infiltration on the Li and Mg isotopic composition of the Horoman Peridotite Massif. Geochim Cosmochim Acta 164:318–332.
    OpenUrl
  21. ↵
    1. Teng FZ
    (2017) Magnesium isotope geochemistry. Rev Mineral Geochem 82:219–287.
    OpenUrlFREE Full Text
  22. ↵
    1. Wang XJ, et al.
    (2017) Mantle transition zone-derived EM1 component beneath NE China: Geochemical evidence from Cenozoic potassic basalts. Earth Planet Sci Lett 465:16–28.
    OpenUrl
  23. ↵
    1. Tian HC, et al.
    (2016) Origin of low δ26Mg basalts with EM-I component: Evidence for interaction between enriched lithosphere and carbonated asthenosphere. Geochim Cosmochim Acta 188:93–105.
    OpenUrl
  24. ↵
    1. Jackson MG,
    2. Dasgupta R
    (2008) Compositions of HIMU, EM1, and EM2 from global trends between radiogenic isotopes and major elements in ocean island basalts. Earth Planet Sci Lett 276:175–186.
    OpenUrl
  25. ↵
    1. Pilson MEQ
    (2013) An Introduction to the Chemistry of the Sea (Cambridge Univ Press, Cambridge), 2nd Ed, p 67.
  26. ↵
    1. Teng FZ,
    2. Wadhwa M,
    3. Helz RT
    (2007) Investigation of magnesium isotope fractionation during basalt differentiation: Implications for a chondritic composition of the terrestrial mantle. Earth Planet Sci Lett 261:84–92.
    OpenUrl
  27. ↵
    1. Chen LM, et al.
    (2018) Magnesium isotopic evidence for chemical disequilibrium among cumulus minerals in layered mafic intrusion. Earth Planet Sci Lett 487:74–83.
    OpenUrl
  28. ↵
    1. Wang SJ,
    2. Teng FZ,
    3. Scott JM
    (2016) Tracing the origin of continental HIMU-like intraplate volcanism using magnesium isotope systematics. Geochim Cosmochim Acta 185:78–87.
    OpenUrl
  29. ↵
    1. Wang SJ,
    2. Teng FZ,
    3. Rudnick RL,
    4. Li SG
    (2015) Magnesium isotope evidence for a recycled origin of cratonic eclogites. Geology 43:1071–1074.
    OpenUrlAbstract/FREE Full Text
  30. ↵
    1. Schulze DJ
    (1989) Constraints on the abundance of eclogite in the upper mantle. J Geophys Res 94:4205–4212.
    OpenUrl
  31. ↵
    1. Jacob DE
    (2004) Nature and origin of eclogite xenoliths from kimberlites. Lithos 77:295–316.
    OpenUrlCrossRef
  32. ↵
    1. Aulbach S,
    2. Viljoen KS
    (2015) Eclogite xenoliths from the Lace kimberlite, Kaapvaal craton: From convecting mantle source to palaeo-ocean floor and back. Earth Planet Sci Lett 431:274–286.
    OpenUrl
  33. ↵
    1. Gale A, et al.
    (2013) The mean composition of ocean ridge basalts. Geochem Geophys Geosyst 14:489–518.
    OpenUrl
  34. ↵
    1. Yang W, et al.
    (2016) Magnesium isotopic composition of the deep continental crust. Am Mineral 100:243–252.
    OpenUrl
  35. ↵
    1. Huang J, et al.
    (2015) Magnesium isotopic compositions of altered oceanic basalts and gabbros from IODP site 1256 at the East Pacific Rise. Lithos 231:53–61.
    OpenUrl
  36. ↵
    1. Su BX, et al.
    (2015) Iron and magnesium isotope fractionation in oceanic lithosphere and sub-arc mantle: Perspectives from ophiolites. Earth Planet Sci Lett 430:523–532.
    OpenUrl
  37. ↵
    1. Wang SJ,
    2. Teng FZ,
    3. Rudnick RL,
    4. Li SG
    (2015) The behavior of magnesium isotopes in low-grade metamorphosed mudrocks. Geochim Cosmochim Acta 165:435–448.
    OpenUrl
  38. ↵
    1. Veizer J,
    2. Hoefs J,
    3. Lowe DR,
    4. Thurston PC
    (1989) Geochemistry of Precambrian carbonates: II. Archean greenstone belts and Archean sea water. Geochim Cosmochim Acta 53:859–871.
    OpenUrlCrossRefPubMed
  39. ↵
    1. Shields G,
    2. Veizer J
    (2002) Precambrian marine carbonate isotope database: Version 1.1. Geochem Geophys Geosyst 3:1–12.
    OpenUrl
  40. ↵
    1. Sumner DY,
    2. Beukes NJ
    (2006) Sequence stratigraphic development of the Neoarchean Transvaal carbonate platform, Kaapvaal Craton, South Africa. S Afr J Geol 109:11–22.
    OpenUrlAbstract/FREE Full Text
  41. ↵
    1. Beukes NJ
    (1987) Facies relations, depositional environments and diagenesis in a major early Proterozoic stromatolitic carbonate platform to basinal sequence, Campbellrand Subgroup, Transvaal Supergroup, Southern Africa. Sediment Geol 54:1–46.
    OpenUrl
  42. ↵
    1. Garapić G, et al.
    (2015) A radiogenic isotopic (He-Sr-Nd-Pb-Os) study of lavas from the Pitcairn hotspot: Implications for the origin of EM-1 (enriched mantle 1). Lithos 228–229:1–11.
    OpenUrlCrossRef
  43. ↵
    1. Castillo PR
    (2015) The recycling of marine carbonates and sources of HIMU and FOZO ocean island basalts. Lithos 216–217:254–263.
    OpenUrl
  44. ↵
    1. Dasgupta R,
    2. Hirschmann MM,
    3. Stalker K
    (2006) Immiscible transition from carbonate-rich to silicate-rich melts in the 3 GPa melting interval of eclogite + CO2 and genesis of silica-undersaturated ocean island lavas. J Petrol 47:647–671.
    OpenUrlCrossRef
  45. ↵
    1. Dasgupta R,
    2. Hirschmann MM,
    3. Smith ND
    (2007) Partial melting experiments of peridotite + CO2 at 3 GPa and genesis of alkalic ocean island basalts. J Petrol 48:2093–2124.
    OpenUrlCrossRef
  46. ↵
    1. Scott JM,
    2. Turnbull IM,
    3. Auer A,
    4. Palin JM
    (2013) The sub-Antarctic Antipodes volcano: A <0.5 Ma HIMU-like Surtseyan volcanic outpost on the edge of the Campbell Plateau, New Zealand. New Zeal J Geol Geop 56:134–153.
    OpenUrl
  47. ↵
    1. Sobolev AV,
    2. Hofmann AW,
    3. Nikogosian IK
    (2000) Recycled oceanic crust observed in ‘ghost plagioclase’ within the source of Mauna Loa lavas. Nature 404:986–990.
    OpenUrlCrossRefPubMed
  48. ↵
    1. Herzberg C, et al.
    (2014) Phantom Archean crust in Mangaia hotspot lavas and the meaning of heterogeneous mantle. Earth Planet Sci Lett 396:97–106.
    OpenUrl
  49. ↵
    1. Dasgupta R
    (2013) Ingassing, storage, and outgassing of terrestrial carbon through geologic time. Rev Mineral Geochem 75:183–229.
    OpenUrlFREE Full Text
  50. ↵
    1. Grassi D,
    2. Schmidt MW
    (2011) The melting of carbonated pelites from 70 to 700 km depth. J Petrol 52:765–789.
    OpenUrlCrossRef
  51. ↵
    1. Wyllie PJ,
    2. Huang WL,
    3. Otto J,
    4. Byrnes AP
    (1983) Carbonation of peridotites and decarbonation of siliceous dolomites represented in the system CaO-MgO-SiO2-CO2 to 30 kbar. Tectonophysics 100:359–388.
    OpenUrlCrossRef
  52. ↵
    1. Kakizawa S,
    2. Inoue T,
    3. Suenami H,
    4. Kikegawa T
    (2015) Decarbonation and melting in MgCO3–SiO2 system at high temperature and high pressure. J Mineral Petrol Sci 110:179–188.
    OpenUrl
  53. ↵
    1. Martin AM,
    2. Hammouda T
    (2011) Role of iron and reducing conditions on the stability of dolomite + coesite between 4.25 and 6 GPa–A potential mechanism for diamond formation during subduction. Eur J Mineral 23:5–16.
    OpenUrlAbstract/FREE Full Text
  54. ↵
    1. Porter KA,
    2. White WM
    (2009) Deep mantle subduction flux. Geochem Geophys Geosyst 10:Q12016.
    OpenUrl
  55. ↵
    1. Hirschmann MM,
    2. Kogiso T,
    3. Baker MB,
    4. Stolper EM
    (2003) Alkalic magmas generated by partial melting of garnet pyroxenite. Geology 31:481–484.
    OpenUrlAbstract/FREE Full Text
  56. ↵
    1. Pertermann M,
    2. Hirschmann MM
    (2003) Anhydrous partial melting experiments on MORB-like eclogite: Phase relations, phase compositions and mineral–melt partitioning of major elements at 2–3 GPa. J Petrol 44:2173–2201.
    OpenUrlCrossRef
  57. ↵
    1. Ghiorso MS,
    2. Hirschmann MM,
    3. Reiners PW,
    4. Kress VC
    (2002) The pMELTS: A revision of MELTS for improved calculation of phase relations and major element partitioning related to partial melting of the mantle to 3 GPa. Geochem Geophys Geosyst 3:1–35.
    OpenUrl
  58. ↵
    1. An YJ, et al.
    (2014) High-precision Mg isotope analyses of low-Mg rocks by MC-ICP-MS. Chem Geol 390:9–21.
    OpenUrl
  59. ↵
    1. Teng FZ, et al.
    (2010) Magnesium isotopic composition of the Earth and chondrites. Geochim Cosmochim Acta 74:4150–4166.
    OpenUrlCrossRef
PreviousNext
Back to top
Article Alerts
Email Article

Thank you for your interest in spreading the word on PNAS.

NOTE: We only request your email address so that the person you are recommending the page to knows that you wanted them to see it, and that it is not junk mail. We do not capture any email address.

Enter multiple addresses on separate lines or separate them with commas.
Recycled ancient ghost carbonate in the Pitcairn mantle plume
(Your Name) has sent you a message from PNAS
(Your Name) thought you would like to see the PNAS web site.
CAPTCHA
This question is for testing whether or not you are a human visitor and to prevent automated spam submissions.
Citation Tools
Recycled ancient ghost carbonate in the Pitcairn mantle plume
Xiao-Jun Wang, Li-Hui Chen, Albrecht W. Hofmann, Takeshi Hanyu, Hiroshi Kawabata, Yuan Zhong, Lie-Wen Xie, Jin-Hua Shi, Takashi Miyazaki, Yuka Hirahara, Toshiro Takahashi, Ryoko Senda, Qing Chang, Bogdan S. Vaglarov, Jun-Ichi Kimura
Proceedings of the National Academy of Sciences Aug 2018, 115 (35) 8682-8687; DOI: 10.1073/pnas.1719570115

Citation Manager Formats

  • BibTeX
  • Bookends
  • EasyBib
  • EndNote (tagged)
  • EndNote 8 (xml)
  • Medlars
  • Mendeley
  • Papers
  • RefWorks Tagged
  • Ref Manager
  • RIS
  • Zotero
Request Permissions
Share
Recycled ancient ghost carbonate in the Pitcairn mantle plume
Xiao-Jun Wang, Li-Hui Chen, Albrecht W. Hofmann, Takeshi Hanyu, Hiroshi Kawabata, Yuan Zhong, Lie-Wen Xie, Jin-Hua Shi, Takashi Miyazaki, Yuka Hirahara, Toshiro Takahashi, Ryoko Senda, Qing Chang, Bogdan S. Vaglarov, Jun-Ichi Kimura
Proceedings of the National Academy of Sciences Aug 2018, 115 (35) 8682-8687; DOI: 10.1073/pnas.1719570115
Digg logo Reddit logo Twitter logo Facebook logo Google logo Mendeley logo
  • Tweet Widget
  • Facebook Like
  • Mendeley logo Mendeley
Proceedings of the National Academy of Sciences: 115 (35)
Table of Contents

Submit

Sign up for Article Alerts

Article Classifications

  • Physical Sciences
  • Earth, Atmospheric, and Planetary Sciences

Jump to section

  • Article
    • Abstract
    • Results
    • Discussion
    • Materials and Methods
    • Acknowledgments
    • Footnotes
    • References
  • Figures & SI
  • Info & Metrics
  • PDF

You May Also be Interested in

Abstract depiction of a guitar and musical note
Science & Culture: At the nexus of music and medicine, some see disease treatments
Although the evidence is still limited, a growing body of research suggests music may have beneficial effects for diseases such as Parkinson’s.
Image credit: Shutterstock/agsandrew.
Scientist looking at an electronic tablet
Opinion: Standardizing gene product nomenclature—a call to action
Biomedical communities and journals need to standardize nomenclature of gene products to enhance accuracy in scientific and public communication.
Image credit: Shutterstock/greenbutterfly.
One red and one yellow modeled protein structures
Journal Club: Study reveals evolutionary origins of fold-switching protein
Shapeshifting designs could have wide-ranging pharmaceutical and biomedical applications in coming years.
Image credit: Acacia Dishman/Medical College of Wisconsin.
White and blue bird
Hazards of ozone pollution to birds
Amanda Rodewald, Ivan Rudik, and Catherine Kling talk about the hazards of ozone pollution to birds.
Listen
Past PodcastsSubscribe
Goats standing in a pin
Transplantation of sperm-producing stem cells
CRISPR-Cas9 gene editing can improve the effectiveness of spermatogonial stem cell transplantation in mice and livestock, a study finds.
Image credit: Jon M. Oatley.

Similar Articles

Site Logo
Powered by HighWire
  • Submit Manuscript
  • Twitter
  • Facebook
  • RSS Feeds
  • Email Alerts

Articles

  • Current Issue
  • Latest Articles
  • Archive

PNAS Portals

  • Anthropology
  • Chemistry
  • Classics
  • Front Matter
  • Physics
  • Sustainability Science
  • Teaching Resources

Information

  • Authors
  • Editorial Board
  • Reviewers
  • Librarians
  • Press
  • Site Map
  • PNAS Updates

Feedback    Privacy/Legal

Copyright © 2021 National Academy of Sciences. Online ISSN 1091-6490