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Research Article

Tuning the quantumness of simple Bose systems: A universal phase diagram

View ORCID ProfileYoussef Kora, View ORCID ProfileMassimo Boninsegni, View ORCID ProfileDam Thanh Son, and View ORCID ProfileShiwei Zhang
  1. aDepartment of Physics, University of Alberta, Edmonton, AB T6G 2E1, Canada;
  2. bKadanoff Center for Theoretical Physics, The University of Chicago, Chicago, IL 60637;
  3. cCenter for Computational Quantum Physics, Flatiron Institute, New York, NY 10010;
  4. dDepartment of Physics, The College of William and Mary, Williamsburg, VA 23187

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PNAS November 3, 2020 117 (44) 27231-27237; first published October 21, 2020; https://doi.org/10.1073/pnas.2017646117
Youssef Kora
aDepartment of Physics, University of Alberta, Edmonton, AB T6G 2E1, Canada;
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  • ORCID record for Youssef Kora
  • For correspondence: ykora@ualberta.ca dtson@uchicago.edu
Massimo Boninsegni
aDepartment of Physics, University of Alberta, Edmonton, AB T6G 2E1, Canada;
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  • ORCID record for Massimo Boninsegni
Dam Thanh Son
bKadanoff Center for Theoretical Physics, The University of Chicago, Chicago, IL 60637;
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  • ORCID record for Dam Thanh Son
  • For correspondence: ykora@ualberta.ca dtson@uchicago.edu
Shiwei Zhang
cCenter for Computational Quantum Physics, Flatiron Institute, New York, NY 10010;
dDepartment of Physics, The College of William and Mary, Williamsburg, VA 23187
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  • ORCID record for Shiwei Zhang
  1. Contributed by Dam Thanh Son, September 17, 2020 (sent for review August 20, 2020; reviewed by Joseph Carlson and Boris Svistunov)

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Significance

Predicting the properties of a quantum-mechanical system of many interacting particles is a major goal of modern science and an outstanding challenge. We consider a compact and versatile model which captures the essential features of a broad class of systems made of particles obeying Bose–Einstein statistics and which allows one to systematically dial up the effect of quantum entanglement in the presence of particle interaction by tuning a single parameter. We are able to obtain exact numerical results for the phase diagrams of these systems. Possible directions for experimental realization of the predictions are discussed.

Abstract

We present a comprehensive theoretical study of the phase diagram of a system of many Bose particles interacting with a two-body central potential of the so-called Lennard-Jones form. First-principles path-integral computations are carried out, providing essentially exact numerical results on the thermodynamic properties. The theoretical model used here provides a realistic and remarkably general framework for describing simple Bose systems ranging from crystals to normal fluids to superfluids and gases. The interplay between particle interactions on the one hand and quantum indistinguishability and delocalization on the other hand is characterized by a single quantumness parameter, which can be tuned to engineer and explore different regimes. Taking advantage of the rare combination of the versatility of the many-body Hamiltonian and the possibility for exact computations, we systematically investigate the phases of the systems as a function of pressure (P) and temperature (T), as well as the quantumness parameter. We show how the topology of the phase diagram evolves from the known case of 4He, as the system is made more (and less) quantum, and compare our predictions with available results from mean-field theory. Possible realization and observation of the phases and physical regimes predicted here are discussed in various experimental systems, including hypothetical muonic matter.

  • statistical physics
  • quantum many-body physics
  • quantum fluids and solids
  • Bose–Einstein condensation
  • superfluidity

Footnotes

  • ↵1To whom correspondence may be addressed. Email: ykora{at}ualberta.ca or dtson{at}uchicago.edu.
  • Author contributions: Y.K., M.B., D.T.S., and S.Z. designed research, performed research, contributed new reagents/analytic tools, analyzed data, and wrote the paper.

  • Reviewers: J.C., Los Alamos National Laboratory; and B.S., University of Massachusetts Amherst.

  • The authors declare no competing interest.

  • See online for related content such as Commentaries.

Data Availability.

There are no data underlying this work.

Published under the PNAS license.

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References

  1. ↵
    1. V. F. Weisskopf
    , About liquids. Trans. N. Y. Acad. Sci. 38, 202–218 (1977).
    OpenUrl
  2. ↵
    1. P. A. M. Dirac
    , Quantum mechanics of many-electron systems. Proc. R. Soc. Lond. A 123, 714–733 (1929).
    OpenUrlCrossRef
  3. ↵
    1. R. P. Feynman
    , Atomic theory of the λ transition in helium. Phys. Rev. 91, 1291–1301 (1953).
    OpenUrlCrossRef
  4. ↵
    1. M. Boninsegni,
    2. L. Pollet,
    3. N. Prokof’ev,
    4. B. Svistunov
    , Role of Bose statistics in crystallization and quantum jamming. Phys. Rev. Lett. 109, 025302 (2012).
    OpenUrlPubMed
  5. ↵
    1. J. De Boer
    , Quantum theory of condensed permanent gases I: The law of corresponding states. Physica 14, 139–148 (1948).
    OpenUrlCrossRef
  6. ↵
    1. M. Dusseault,
    2. M. Boninsegni
    , Atomic displacements in quantum crystals. Phys. Rev. B 95, 104518 (2017).
    OpenUrl
  7. ↵
    1. M. Boninsegni
    , Ground state phase diagram of parahydrogen in one dimension. Phys. Rev. Lett. 111, 205303 (2013).
    OpenUrl
  8. ↵
    1. C. J. Pethik,
    2. H. Smith
    , Bose-Einstein Condensation in Dilute Gases (Cambridge University Press, Cambridge, UK, 2005).
  9. ↵
    1. C. Yuan et al.
    , Unconventional superconductivity in magic-angle graphene superlattices. Nature 556, 43–50 (2018).
    OpenUrlCrossRefPubMed
  10. ↵
    1. C. Yuan et al.
    , Correlated insulator behaviour at half-filling in magic-angle graphene superlattices. Nature 556, 80–84 (2018).
    OpenUrlCrossRefPubMed
  11. ↵
    1. D. Kleppner,
    2. F.M. Pipkin
    1. P. O. Egan
    , “Muonic helium” in Atomic Physics, D. Kleppner, F.M. Pipkin, Eds. (Plenum Press, New York, NY, 1981), vol. 7, pp. 373–384.
    OpenUrl
  12. ↵
    1. H. Masaki,
    2. H. Aghai-Khozani,
    3. A. Sótér,
    4. A. Dax,
    5. D. Barna
    , Laser spectroscopy of pionic helium atoms. Nature 581, 37–41 (2020).
    OpenUrl
  13. ↵
    1. T. Tajima
    , Muonic superdense matter and channeled beams. Muon Cat. Fusion 1, 257 (1987).
    OpenUrl
  14. ↵
    1. H. Mark,
    2. L. Wood
    1. J. A. Wheeler
    , “Nanosecond matter” in Energy in Physics, War and Peace: A Festschrift Celebrating Edward Teller’s 80th Birthday, H. Mark, L. Wood, Eds. (Kluwer, Dordrecht, The Netherlands, 1988), pp. 266–290.
  15. ↵
    1. D. Thanh Son,
    2. M. Stephanov,
    3. H.-U. Yee
    , The phase diagram of ultra quantum liquids. arxiv.org/abs/2006.01156 (2 June 2020).
  16. ↵
    1. M. Boninsegni,
    2. N. V. Prokof’ev,
    3. B. V. Svistunov
    , Worm algorithm for continuous-space path integral Monte Carlo simulations. Phys. Rev. Lett. 96, 070601 (2006).
    OpenUrlPubMed
  17. ↵
    1. M. Boninsegni,
    2. N. V. Prokof’ev,
    3. B. V. Svistunov
    , Worm algorithm and diagrammatic Monte Carlo: A new approach to continuous-space path integral Monte Carlo simulations. Phys. Rev. E 74, 036701 (2006).
    OpenUrl
  18. ↵
    1. F. Mezzacapo,
    2. M. Boninsegni
    , Superfluidity and quantum melting of p-H2 clusters. Phys. Rev. Lett. 97, 045301 (2006).
    OpenUrlPubMed
  19. ↵
    1. F. Mezzacapo,
    2. M. Boninsegni
    , Structure, superfluidity, and quantum melting of hydrogen clusters. Phys. Rev. A 75, 033201 (2007).
    OpenUrl
  20. ↵
    1. L. H. Nosanow,
    2. L. J. Parish,
    3. F. J. Pinski
    , Zero-temperature properties of matter and the quantum theorem of corresponding states: The liquid-to-crystal phase transition for Fermi and Bose systems. Phys. Rev. B 11, 191–204 (1975).
    OpenUrl
  21. ↵
    1. M. D. Miller,
    2. L. H. Nosanow,
    3. L. J. Parish
    , Zero-temperature properties of matter and the quantum theorem of corresponding states. II. The liquid-to-gas phase transition for Fermi and Bose systems. Phys. Rev. B 15, 214–229 (1977).
    OpenUrl
  22. ↵
    1. E. L. Pollock,
    2. D. M. Ceperley
    , Path-integral computation of superfluid densities. Phys. Rev. B 36, 8343–8352 (1987).
    OpenUrl
  23. ↵
    1. D. M. Ceperley
    , Path integrals in the theory of condensed helium. Rev. Mod. Phys. 67, 279–355 (1995).
    OpenUrlCrossRef
  24. ↵
    1. A. Cuccoli,
    2. A. Macchi,
    3. V. Tognettti,
    4. R. Vaia
    , Monte-Carlo computations of the quantum kinetic energy of rare gas solids. Phys. Rev. B 47, 14923–14931 (1993).
    OpenUrl
  25. ↵
    1. M. H. Müser,
    2. P. Nielaba,
    3. K. Binder
    , Path-integral Monte Carlo study of crystalline Lennard-Jones systems. Phys. Rev. B 51, 2723–2731 (1995).
    OpenUrl
  26. ↵
    1. R. P. Feynman,
    2. A. R. Hibbs
    , Quantum Mechanics and Path Integrals (McGraw-Hill, New York, NY, 1965).
  27. ↵
    1. M. Takahashi,
    2. M. Imada
    , Finite temperature properties of 4He by the quantum Monte Carlo method. J. Phys. Soc. Japan 53, 3871–3877 (1984).
    OpenUrl
  28. ↵
    1. M. Boninsegni
    , Permutation sampling in path integral Monte Carlo. J. Low Temp. Phys. 141, 27–46 (2005).
    OpenUrl
  29. ↵
    1. S. Moroni,
    2. F. Pederiva,
    3. S. Fantoni,
    4. M. Boninsegni
    , Equation of state of solid 3He. Phys. Rev. Lett. 84, 2650–2653 (2000).
    OpenUrlPubMed
  30. ↵
    1. R. K. Pathria,
    2. P. D. Beale
    , Statistical Mechanics (Academic Press, Boston, MA, ed. 3, 2011).
  31. ↵
    1. J. Wilks
    , The Properties of Liquid and Solid Helium (Oxford University Press, New York, NY, 1967).
  32. ↵
    1. R. J. Donnelly,
    2. C. F. Barenghi
    , The observed properties of liquid helium at the saturated vapor pressure. J. Phys. Chem. Ref. Data 27, 1217–1274 (1998).
    OpenUrlCrossRef
  33. ↵
    1. R. A. Aziz,
    2. V. P. S. Nain,
    3. J. S. Carley,
    4. W. L. Taylor,
    5. G. T. McConville
    , An accurate intermolecular potential for helium. J. Chem. Phys. 70, 4330–4342 (1979).
    OpenUrl
  34. ↵
    1. F. J. Gómez,
    2. J. Sesma
    , Scattering length for Lennard-Jones potentials. Eur. Phys. J. D 66, 6 (2012).
    OpenUrl
  35. ↵
    1. W. Zwerger
    , Quantum-unbinding near a zero temperature liquid–gas transition. J. Stat. Mech. Theory Exp. 2019, 103104 (2019).
    OpenUrl
  36. ↵
    1. P. M. A. Mestrom,
    2. V. E. Colussi,
    3. T. Secker,
    4. G. P. Groeneveld,
    5. S. J. J. M. F. Kokkelmans
    , Van der Waals universality near a quantum tricritical point. Phys. Rev. Lett. 124, 143401 (2020).
    OpenUrl
  37. ↵
    1. M. Boninsegni
    , Search for superfluidity in supercooled liquid parahydrogen. Phys. Rev. B 97, 054517 (2018).
    OpenUrl
  38. ↵
    1. F. Caupin,
    2. S. Balibar,
    3. H. J. Maris
    , Limits of metastability of liquid helium. Physica B Condens. Matter 329–333, 356–359 (2003).
    OpenUrl
  39. ↵
    1. F. Werner et al.
    , Liquid helium up to 160 bar. J. Low Temp. Phys. 136, 93–116 (2004).
    OpenUrl
  40. ↵
    1. S. Moroni,
    2. M. Boninsegni
    , Condensate fraction in liquid 4He. J. Low Temp. Phys. 136, 129–137 (2004).
    OpenUrlCrossRef
  41. ↵
    1. M. Boninsegni,
    2. N. V. Prokof’ev,
    3. B. V. Svistunov
    , Superglass phase of 4He. Phys. Rev. Lett. 96, 105301 (2006).
    OpenUrlCrossRefPubMed
  42. ↵
    1. E. R. Grilly,
    2. R. L. Mills
    , Melting properties of 3He and 4He up to 3500 kg/cm2. Ann. Phys. (N.Y.) 8, 1–23 (1959).
    OpenUrl
  43. ↵
    1. M. Boninsegni,
    2. N. Prokof’ev
    , Supersolids, what and where are they?. Rev. Mod. Phys. 84, 759–776 (2012).
    OpenUrl
  44. ↵
    1. M. Boninsegni
    , Supersolid phases of cold atom assemblies. J. Low Temp. Phys. 168, 137–149 (2012).
    OpenUrl

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Tuning the quantumness of simple Bose systems: A universal phase diagram
Youssef Kora, Massimo Boninsegni, Dam Thanh Son, Shiwei Zhang
Proceedings of the National Academy of Sciences Nov 2020, 117 (44) 27231-27237; DOI: 10.1073/pnas.2017646117

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Tuning the quantumness of simple Bose systems: A universal phase diagram
Youssef Kora, Massimo Boninsegni, Dam Thanh Son, Shiwei Zhang
Proceedings of the National Academy of Sciences Nov 2020, 117 (44) 27231-27237; DOI: 10.1073/pnas.2017646117
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