Table 1.

Thermodynamic and kinetic parameters relevant to intramolecular ET and mixed valency, extracted from Hush analysis of IVCT bands of 1b and 1c

Cubaneνmax, cm–1Δν1/2, cm–1Δν01/2, cm–1ΓHab, cm–1λ, eVΔG*, cm–1kET, s–1
1b5,4002,6703,5300.242730.671,0903.22 × 1012
1c6,0003,4503,7200.073940.741,1303.17 × 1012