Table 2.

Exciplex decay rates and energetics

CompoundDecay rate ExciplexDonor IP , eVAcceptor EA § , eVIP–EA, eV
CpG8.5CG+ 7.77−0.057.82
ApU5.8A+U 8.260.208.06
ApC2.3A+C 8.26−0.058.31
ApG1.0A+G 8.26−0.759.01
AG+ 7.77−0.358.12
ApA1.0A+A 8.26−0.358.61
  • Relative to the rate for ApA.

  • Adiabatic IP from ref. 51.

  • §Calculated adiabatic EA from ref. 52.