Table 2

Kinetics for the reoxidation of reduced enzymes and flavins by nitrate esters

CompoundOYE 1Y196F OYE 1H191N OYE 1Flavin
GTNkox 40 s−1kox 80 s−1kox 0.013 s−1kox 145 M−1 s−1
Kd 2.7 mMKd 33 mMKd 0.5 mM
PDNkox 7 s−1kox 5.8 M−1 s−1
Kd 12 mM